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Breakage of ether linkage during vinylation of diethylene glycol

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Diethylene glycol gives a small amount of ethylene glycol on heating with alkali. The process is appreciably intensified in the presence of acetylene.

  2. 2.

    A scheme is suggested showing the accelerating effect of acetylene on the breakage of the ether linkage, based on the supposition that the ether oxygen atom is able to interact with acetylene as a nucleophile.

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Literature cited

  1. M. F. Shostakovskii, A. S. Atavin, and B. A. Trofimov, Zh. Obshch. Khim.,34, 2089 (1964).

    Google Scholar 

  2. B. A. Trofimov, Thesis, Irkutsk (1965).

  3. R. L. Zimmerman, G. D. Jones, and W. R. Nummy, Ind. and Eng. Chem.,55, 296 (1963).

    Google Scholar 

  4. V. N. Antonov, I. N. Azerbaev, M. F. Shostakovskii, R. D. Yakubov, and A. S. Atavin. Author's Certificate No. 180579, 1963; Byul. Izobr., No. 8 (1966).

  5. G. D. Jones, W. R. Nummy, and R. L. Zimmerman, J. Amer. Chem. Soc., Div. Org. Coatings Chem. Preprints,23, (1), 207 (1963).

    Google Scholar 

  6. Determination of Structure of Organic Compounds by Physical and Chemical Methods [in Russian], A. Weissburger (editor), Izd. Khimiya (1967), p. 252.

  7. S. V. Amosova, A. S. Atavin, and B. A. Trofimov, Izv. Akad. Nauk SSSR, Ser. Khim., 619 (1967).

  8. Tsutomu Furuga, J. Chromatogr.,19, 610 (1965).

    Google Scholar 

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Author information

Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    A. S. Atavin, S. V. Amosova, O. N. Vylegzhanin, V. V. Keiko, B. A. Trofimov & R. D. Yakubov

Authors
  1. A. S. Atavin
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  2. S. V. Amosova
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  3. O. N. Vylegzhanin
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  4. V. V. Keiko
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  5. B. A. Trofimov
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  6. R. D. Yakubov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 149–152, January, 1970.

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Atavin, A.S., Amosova, S.V., Vylegzhanin, O.N. et al. Breakage of ether linkage during vinylation of diethylene glycol. Russ Chem Bull 19, 140–142 (1970). https://doi.org/10.1007/BF00913941

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  • DOI: https://doi.org/10.1007/BF00913941

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