Monatshefte für Chemie / Chemical Monthly

, Volume 106, Issue 6, pp 1553–1557 | Cite as

Polarographische Untersuchungen an Thallium(I)—Äthan-1,2-dithiolkomplexen

  • R. S. Saxena
  • S. K. Bhatia
Anorganische, Struktur- und Physikalische Chemie

Polarographic study of thallium(I)—Ethane-1,2-dithiol complexes

Abstract

Complexation of thallium(I) with ethane-1,2-dithiol has been studied polarographically in 25% ethanol, 0.5M-NaClO4, 0.01M-HClO4 and 0.002% Triton X-100. Thallium in presence of ethane-1,2-dithiol, reduces reversibly at d.m.e. and the plateau current is diffusion-controlled. The successive formation of two complexes, 1∶1 and 1∶2, is indicated byDeford andHume's method. The overall changes in the thermodynamic parameters viz. ΔG, ΔH, ΔS accompanying complexation reactions have also been reported.

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Literatur

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Copyright information

© Springer-Verlag 1975

Authors and Affiliations

  • R. S. Saxena
    • 1
  • S. K. Bhatia
    • 1
  1. 1.Department of ChemistryMalaviya Regional Engineering CollegeJaipurIndien

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