Reactions of fluoroolefins Communication 8. Reactions of perfluorovinylmagnesium halides

  • I. L. Knuniants
  • R. N. Sterlin
  • R. D. Iatsenko
  • L. N. Pinkina
Article

Summary

  1. 1.

    It was shown that perfluorovinylmagnesium iodide and perfluorovinylmagnesium bromide can be prepared in yields of 70 and 45%, respectively, in a reaction medium of ether or tetrahydrofuran.

     
  2. 2.

    A new method was found for the preparation of perfluoroacrylic acid; the method comprises the reaction of CF2=CFMgI with carbon dioxide.

     

Keywords

Ether Dioxide Carbon Dioxide Bromide Iodide 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. [1]
    F. Runge, Organomagnesium Compounds, ONTI, 1937.Google Scholar
  2. [2]
    T. Brice et al., J. Amer. Chem. Soc. 68, 968 (1946).Google Scholar
  3. [3]
    R. Haszeldine et al., J. Chem. Soc. 1952, 3423; 1953, 1748; 1954, 1273.Google Scholar
  4. [4]
    J. Park et al., J. Amer. Chem. Soc. 78, 59 (1956).Google Scholar
  5. [5]
    R. Haszeldine. J. Chem. Soc. 1952, 3423.Google Scholar
  6. [6]
    A. Henne and C. Foche, J. Amer. Chem. Soc. 76, 479 (1954).Google Scholar
  7. [7]
    F. Swarts, Bull. Acad. roy. Belgique 34, 307 (1897).Google Scholar
  8. [8]
    J. Park et al., J. Amer. Chem. Soc. 78, 711 (1951).Google Scholar

Copyright information

© Consultants Bureau Inc. 1959

Authors and Affiliations

  • I. L. Knuniants
  • R. N. Sterlin
  • R. D. Iatsenko
  • L. N. Pinkina

There are no affiliations available

Personalised recommendations