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Reactions of fluoroolefins Communication 8. Reactions of perfluorovinylmagnesium halides

  • I. L. Knuniants
  • R. N. Sterlin
  • R. D. Iatsenko
  • L. N. Pinkina
Article

Summary

  1. 1.

    It was shown that perfluorovinylmagnesium iodide and perfluorovinylmagnesium bromide can be prepared in yields of 70 and 45%, respectively, in a reaction medium of ether or tetrahydrofuran.

     
  2. 2.

    A new method was found for the preparation of perfluoroacrylic acid; the method comprises the reaction of CF2=CFMgI with carbon dioxide.

     

Keywords

Ether Dioxide Carbon Dioxide Bromide Iodide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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    F. Runge, Organomagnesium Compounds, ONTI, 1937.Google Scholar
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    R. Haszeldine et al., J. Chem. Soc. 1952, 3423; 1953, 1748; 1954, 1273.Google Scholar
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    J. Park et al., J. Amer. Chem. Soc. 78, 59 (1956).Google Scholar
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    R. Haszeldine. J. Chem. Soc. 1952, 3423.Google Scholar
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    J. Park et al., J. Amer. Chem. Soc. 78, 711 (1951).Google Scholar

Copyright information

© Consultants Bureau Inc. 1959

Authors and Affiliations

  • I. L. Knuniants
  • R. N. Sterlin
  • R. D. Iatsenko
  • L. N. Pinkina

There are no affiliations available

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