Reactions of fluoroolefins Communication 8. Reactions of perfluorovinylmagnesium halides

  • I. L. Knuniants
  • R. N. Sterlin
  • R. D. Iatsenko
  • L. N. Pinkina


  1. 1.

    It was shown that perfluorovinylmagnesium iodide and perfluorovinylmagnesium bromide can be prepared in yields of 70 and 45%, respectively, in a reaction medium of ether or tetrahydrofuran.

  2. 2.

    A new method was found for the preparation of perfluoroacrylic acid; the method comprises the reaction of CF2=CFMgI with carbon dioxide.



Ether Dioxide Carbon Dioxide Bromide Iodide 
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Literature cited

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    F. Runge, Organomagnesium Compounds, ONTI, 1937.Google Scholar
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    T. Brice et al., J. Amer. Chem. Soc. 68, 968 (1946).Google Scholar
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    R. Haszeldine et al., J. Chem. Soc. 1952, 3423; 1953, 1748; 1954, 1273.Google Scholar
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    J. Park et al., J. Amer. Chem. Soc. 78, 59 (1956).Google Scholar
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    A. Henne and C. Foche, J. Amer. Chem. Soc. 76, 479 (1954).Google Scholar
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    F. Swarts, Bull. Acad. roy. Belgique 34, 307 (1897).Google Scholar
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    J. Park et al., J. Amer. Chem. Soc. 78, 711 (1951).Google Scholar

Copyright information

© Consultants Bureau Inc. 1959

Authors and Affiliations

  • I. L. Knuniants
  • R. N. Sterlin
  • R. D. Iatsenko
  • L. N. Pinkina

There are no affiliations available

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