Reaction of perfluoronitrosoalkanes with esters of phosphorous acid

  • B. L. Dyatkin
  • E. P. Mochalina
  • Yu. S. Konstantinov
  • S. R. Sterlin
  • I. L. Knunyants
Organic and Biological Chemistry
  • 16 Downloads

Conclusions

  1. 1.

    Depending on the structure of the perfluoronitrosoalkanes, their reaction with triethyl phosphite leads to obtaining fluorine-containing phosphazo compounds, the ethyl ethers of oximes of perfluoro ketones, and the oxides of perfluoronitriles.

     
  2. 2.

    Some new examples of a chemical analogy between the perfluoronitrosoalkanes and perfluoro ketones were discovered.

     
  3. 3.

    The obtained results are in agreement with the concept that the phosphite initially attacks the nitrogen atom of the nitroso group.

     

Keywords

Oxide Nitrogen Ether Ester Ethyl 

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Copyright information

© Consultants Bureau 1968

Authors and Affiliations

  • B. L. Dyatkin
    • 1
  • E. P. Mochalina
    • 1
  • Yu. S. Konstantinov
    • 1
  • S. R. Sterlin
    • 1
  • I. L. Knunyants
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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