Conclusions
-
1.
Triallylboron reacts with acetylenic hydrocarbons at 100–130° to yield 3-borabicyclo[3.3.1]non-6-ene derivatives, the hydrogenation of which leads to compounds of the 3-borabicyclo[3.3.1]nonane series.
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2.
Compounds of the 3-borabicyclo[3.3.1]nonane series can be successfully used to obtain cis-1,3-derivatives of cyclohexene and cyclohexane.
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3.
Triallylboron adds to methylacetylene at 20° with the formation of diallyl (2-methyl-1,4-pentadienyl) boron.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2290–2297, October, 1967.
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Mikhailov, B.M., Bubnov, Y.N. & Frolov, S.I. Organoboron compounds. Russ Chem Bull 16, 2193–2199 (1967). https://doi.org/10.1007/BF00913304
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DOI: https://doi.org/10.1007/BF00913304