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Monatshefte für Chemie / Chemical Monthly

, Volume 109, Issue 5, pp 1139–1144 | Cite as

Die IR-Spektren von Kobalt-, Nickel- und Zink-Orthovanadat

  • Enrique J. Baran
  • Irma L. Botto
  • Juan F. Ramos
  • Pedro J. Aymonino
Anorganische, Struktur- und physikalische Chemie

The IR-spectra of the orthovanadates of cobalt, nickel and zinc

Abstract

Infrared spectra of crystalline Co3(VO4)2, Ni3(VO4)2 and Zn3(VO4)2 as well as the laser-Raman spectrum of the last mentioned compound are reported and discussed. A series of solid solutions of the type (Zn/Ni)3(VO4)2 have also been prepared and investigated, in order to obtain a wider insight into the spectroscopic behaviour of this class of compounds in the 500-250 cm−1 region. Comparisons with the formerly investigated isotypic Mg3(VO4)2 allows to confirm some of the earlier statements and assignments in the light of additional experimental information.

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Copyright information

© Springer-Verlag 1978

Authors and Affiliations

  • Enrique J. Baran
    • 1
  • Irma L. Botto
    • 1
  • Juan F. Ramos
    • 1
  • Pedro J. Aymonino
    • 1
  1. 1.Cátedra de Química Inorgánica, Facultad de Ciencias ExactasUniversidad Nacional de La PlataLa PlataArgentina

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