Monatshefte für Chemie / Chemical Monthly

, Volume 109, Issue 5, pp 1139–1144 | Cite as

Die IR-Spektren von Kobalt-, Nickel- und Zink-Orthovanadat

  • Enrique J. Baran
  • Irma L. Botto
  • Juan F. Ramos
  • Pedro J. Aymonino
Anorganische, Struktur- und physikalische Chemie

The IR-spectra of the orthovanadates of cobalt, nickel and zinc


Infrared spectra of crystalline Co3(VO4)2, Ni3(VO4)2 and Zn3(VO4)2 as well as the laser-Raman spectrum of the last mentioned compound are reported and discussed. A series of solid solutions of the type (Zn/Ni)3(VO4)2 have also been prepared and investigated, in order to obtain a wider insight into the spectroscopic behaviour of this class of compounds in the 500-250 cm−1 region. Comparisons with the formerly investigated isotypic Mg3(VO4)2 allows to confirm some of the earlier statements and assignments in the light of additional experimental information.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 2.
    E. J. Baran, Mh. Chem.106, 1 (1975).Google Scholar
  2. 3.
    R. Gopal undC. Calvo, Canad. J. Chem.49, 3056 (1971).Google Scholar
  3. 4.
    E. E. Sauerbrei, R. Faggiani undC. Calvo, Acta Crystallogr.B29, 2304 (1973).Google Scholar
  4. 5.
    H. Krishnamachari undC. Calvo, Canad. J. Chem.49, 1629 (1971).Google Scholar
  5. 6.
    J. Preudhomme undP. Tarte, Spectrochim. Acta28A, 69 (1972).Google Scholar
  6. 7.
    M. Th. Paques-Ledent, Chem. Phys. Letters35, 375 (1975).Google Scholar
  7. 8.
    J. Preudhomme undP. Tarte, Spectrochim. Acta27 A, 1817 (1971).Google Scholar
  8. 9.
    N. Weinstock, H. Schulze undA. Müller, J. chem. Phys.59, 5063 (1973).Google Scholar
  9. 10.
    A. Müller, N. Weinstock undE. J. Baran, Anales Asoc. Quím. Argent.64, 239 (1976).Google Scholar
  10. 11.
    C. Brisi, Ann. Chimica47, 806 (1957).Google Scholar
  11. 12.
    C. Brisi, La Ric. Scientif.30, 1339 (1960).Google Scholar

Copyright information

© Springer-Verlag 1978

Authors and Affiliations

  • Enrique J. Baran
    • 1
  • Irma L. Botto
    • 1
  • Juan F. Ramos
    • 1
  • Pedro J. Aymonino
    • 1
  1. 1.Cátedra de Química Inorgánica, Facultad de Ciencias ExactasUniversidad Nacional de La PlataLa PlataArgentina

Personalised recommendations