Abstract
In view of the biological importance of substituted thioureas as electron donors, the charge-transfer interaction of 1-piperidinethiocarboxanilide with 1, 3, 5-trinitrobenzene and 2, 4, 6-trinitrotoluene was studied. From the electronic spectra in carbon tetrachloride, values have been obtained for the formation constant of the 1∶1 complexes and data for the changes in enthalpy, free energy and entropy are presented.
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Kannan, S., Raghavendran, A. & Subbaratnam, N.R. Charge-transfer interaction between 1-piperidinethiocarboxanilide with trinitrobenzene and trinitrotoluene. Monatshefte für Chemie 108, 577–579 (1977). https://doi.org/10.1007/BF00912802
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DOI: https://doi.org/10.1007/BF00912802