Skip to main content
SpringerLink
Log in

Die Kristallstruktur des N,N-Dijodformamids HCONJ2

The crystal structure of N,N-diiodoformamide HCONI2

  • Anorganische, Struktur- und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The crystal structure of N,N-Diiodoformamide, HCONI2, has been determined from three-dimensional diffractometer data and refined to a conventionalR-value of 4.1%. The crystals are orthorhombic, space group Pn 21a,Z=4, with the unit cell parametersa=10.758,b=7.075,c=6.671 Å. The molecules are connected by intermolecular I−O-bonds forming chains along thea-axis. Between the chains exist weaker I−O-contacts which link the chains to form layers perpendieular to theb-axis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literatur

  1. H. Hartl, H. Bärnighausen undJ. Jander, Z. anorg. allg. Chem.357, 225 (1968).

    Google Scholar 

  2. W. Gottardi, Mh. Chem.105, 611 (1974).

    Google Scholar 

  3. International Tables for X-Ray Crystallography, Vol. I. Birmingham: The Kynoch Press. 1969.

  4. W. C. Hamilton, Acta Cryst.18, 502 (1965).

    Google Scholar 

  5. H. P. Hanson, F. Herman, J. D. Lea undS. Skillman, Acta Cryst.17, 1040 (1964).

    Google Scholar 

  6. International Tables for X-Ray Crystallography, Vol. III. Birmingham: The Kynoch Press. 1967.

  7. C. D. Schmulbach undR. S. Drago, J. Amer. Chem. Soc.82, 4484 (1960).

    Google Scholar 

  8. J. Ladell undB. Post, Acta Cryst7, 559 (1954).

    Google Scholar 

  9. L. Pauling, Die Natur der chemischen Bindung, S. 213, 245. Wienheim: Verlag Chemie. 1964.

    Google Scholar 

  10. R. S. Mulliken, J. Amer. Chem. Soc.72 600 (1950).

    Google Scholar 

  11. E. H. Wiebenga undD. Kracht, Inorg. Chem.8, 738 (1969).

    Google Scholar 

  12. W. C. Hamilton, Acta Cryst.18, 866 (1965);W. A. Denne undR. W. H. Small, Acta Cryst.B 27, 1094 (1971).

    Google Scholar 

  13. C. C. Costain undJ. M. Dowling, J. Chem. Phys.32, 158 (1960).

    Google Scholar 

  14. K. Venkata Ramiah undV. Venkata Chalapathi, Proc. Indian Acad. Sci. SectionA 58, 233 (1963).

    Google Scholar 

  15. H. Yamada undK. Kozima, J. Amer. Chem. Soc.82, 1543 (1960).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Anorganisch-Chemischen Institut der Universität Heidelberg, Im Neuenheimer Feld 7, D-6900, Heidelberg, Bundesrepublik Deutschland

    H. Pritzkow

Authors
  1. H. Pritzkow
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Mit 1 Abbildung

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pritzkow, H. Die Kristallstruktur des N,N-Dijodformamids HCONJ2 . Monatshefte für Chemie 105, 621–628 (1974). https://doi.org/10.1007/BF00912613

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00912613

Search

Navigation