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Die laminare Strömung als Mittel zur Orientierung gelöster Moleküle; Untersuchungen an α-Poly-γ-benzyl-l-glutamat

Determination of the direction of transition moments in oblong molecules by measurement of infrared dichroism, V: Orientation of molecules in solution by means of laminar flow; Investigations on α-Poly-γ-benzyl-l-glutamate

Über die Bestimmung der Richtung von Übergangsmomenten in länglichen Molekülen aus Messungen des IR-Dichroismus, 5. Mitt

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Starting from relations about the motion of suspended ellipsoidal molecules a method is developed allowing the calculation of the angle between direction of transition moment and longitudinal axis of the molecule from the dichroic ratio and some molecular and flow data. The method is tested on three normal modes of α-poly-γ-benzyl-l-glutamate (ϑ-NH, amid I, amid II). The results are in good agreement with values in the literature.

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  1. Institut für Allgemeine Chemie der Technischen Hochschule Wien, Lehárgasse 4, A-1060, Wien, Österreich

    G. Bauer

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  1. G. Bauer
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Bauer, G. Die laminare Strömung als Mittel zur Orientierung gelöster Moleküle; Untersuchungen an α-Poly-γ-benzyl-l-glutamat. Monatshefte für Chemie 105, 457–473 (1974). https://doi.org/10.1007/BF00912598

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  • DOI: https://doi.org/10.1007/BF00912598

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