Catalytic disproportionation of alkyl(and alkenyl)dichlorosilanes

  • A. D. Petrov
  • V. M. Vdovin


  1. 1.

    The disproportionation of alkyl(and alkenyl)dichlorosilanes in presence of pyridine or adiponitrile as catalyst can be used as a method for the synthesis of alkyl(and alkenyl)monochlorosilanes.

  2. 2.

    It was found that the rate of the disproportionation of the alkyl(and alkenyl)dichlorosilanes depends on the character of the hydrocarbon group attached to silicon, and it was shown that it is greatest in the case of alkenyl groups having the double bond in the γ-position with respect to the silicon atom.



Silicon Hydrocarbon Pyridine Double Bond Disproportionation 
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Copyright information

© Consultants Bureau Enterprises, Inc. 1961

Authors and Affiliations

  • A. D. Petrov
    • 1
  • V. M. Vdovin
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

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