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Character of the electronic structure of metal-like compounds of transition metals with a cementite structure

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Abstract

The x-ray K emission spectra in compounds of transition metals with a cementite structure show considerable similarity. The Kβ5 spectra of Fe, Co, and Ni in Fe3C, Co3B and Ni3B and the Kβ 5 spectrum of manganese in (Fe0.64Mn0.36)3C were studied. A joint examination of the x-ray spectral characteristics and certain physical properties shows that binding of the atoms of the metal and nonmetal in these compounds is accomplished at a high degree of fillingof the d-like bond of the valence spectrum.

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Authors and Affiliations

  1. K. D. Ushinskii Odessa State Pedagogical Institute, USSR

    M. P. Arbuzov, B. I. Kotlyar, T. B. Shashkina, G. V. Zolotareva & M. M. Yatsura

Authors
  1. M. P. Arbuzov
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  2. B. I. Kotlyar
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  3. T. B. Shashkina
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  4. G. V. Zolotareva
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  5. M. M. Yatsura
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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 52–55, June, 1972.

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Arbuzov, M.P., Kotlyar, B.I., Shashkina, T.B. et al. Character of the electronic structure of metal-like compounds of transition metals with a cementite structure. Soviet Physics Journal 15, 821–824 (1972). https://doi.org/10.1007/BF00912217

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  • DOI: https://doi.org/10.1007/BF00912217

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