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Direction of the addition of HBr and HI to allyl- and (2-methylallyl)-chlorosilanes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

Irrespective of the presence or absence of benzoyl peroxide, hydrogen bromide adds to allylchlorosilanes Cln(CH3)3-nSiCH2CH=CH2 exclusively in accordance with Markovnikov's rule when n=0 and 1 and only in the opposite direction when n=3. When n=2, hydrogen bromide may add both in accordance with the rule, and also against the rule when benzoyl peroxide is used. For all values ofn, hydrogen iodide adds to allylchlorosilanes exclusively in accordance with Markovnikov's rule.

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Authors and Affiliations

  1. N.D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    V. F. Mironov

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  1. V. F. Mironov
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Mironov, V.F. Direction of the addition of HBr and HI to allyl- and (2-methylallyl)-chlorosilanes. Russ Chem Bull 8, 1781–1783 (1959). https://doi.org/10.1007/BF00912124

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  • DOI: https://doi.org/10.1007/BF00912124

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