Summary
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1.
aci-1,1,1,3-Tetranitroalkanes, prepared by the action of trinitromethane on 2-nitro-1-alkenes, can be isomerized into the corresponding true nitro compounds.
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2.
A general method was developed for the synthesis of 1,1,1,3-tetranitroalkanes.
Literature cited
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H.E. Zimmerman and T.E. Newins, J. Am. Chem. Soc. 79, 6559 (1957).
J. Brown, Jr., J. Am. Chem. Soc. 77, 6341 (1955).
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Novikov, S.S., Korsakova, I.S. & Babievskii, K.K. Reaction of trinitromethane with 2-nitro-1-alkenes. Russ Chem Bull 8, 1764–1765 (1959). https://doi.org/10.1007/BF00912117
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DOI: https://doi.org/10.1007/BF00912117