Summary
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1.
An investigation was made of the transformations of some individual naphthene hydrocarbons and of cyclohexene in presence of benzene over synthetic aluminum silicates.
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2.
At 525–530° and 10–15 atm, the transformations of these cyclic hydrocarbons in presence of benzene are directed mainly toward the formation of aromatic hydrocarbons of low molecular weight: toluene, xylenes, and others. The presence of benzene has a favorable effect on the aromatization of cyclohexanes and cyclohexene.
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3.
In the catalytic treatment of naphthenes, aromatization is accompanied, to some extent, by the destructive alkylation of benzene and by the cracking and isomerization of the original cycloalkanes.
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Mamedaliev, G.M., Topchiev, A.V. & Aliev, S.M. Catalytic transformations of individual naphthene hydrocarbons and cyclohexene in presence of benzene. Russ Chem Bull 8, 1717–1726 (1959). https://doi.org/10.1007/BF00912108
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DOI: https://doi.org/10.1007/BF00912108