Abstract
The constitution of the ternary systems V−Fe−N, V−Co−N, and V−Ni−N has been investigated by X-raymethods, metallographically and partly by microprobe analysis. Isothermal sections are presented for 1100°C and 1200°C respectively. Ternary complex nitrides have been observed in the systems V−Co−N and V−Ni−N. The compounds with formula V4Co2N (a=10.88–10.83±0.01 Å) and V4Ni2N (a=10.88−10.86±0.01 Å) crystallize with the partly filled Ti2Ni-structure.
Similar content being viewed by others
Literatur
H. Holleck undF. Thümmler, Planseeber. Pulvermet.23, 175 (1975).
H. Holleck undF. Thümmler, Mh. Chem.98, 133 (1967).
H. Hahn, Z. Anorg. Chem.258, 58 (1949).
G. Brauer undW. A. Schnell, J. Less Common Metals6, 326 (1964).
J. L. Henry, S. A. O. Hare, R. A. McCune undM. P. Krug, J. Less Common Metals25, 39 (1971).
D. I. Potter undC. Altstetter, Acta Met.19, 881 (1971).
D. I. Potter, H. Epstein undB. Goldstein, Met. Trans.5, 2075 (1974).
H. hansen undK. Anderko, Constitution of Binary Alloys. New York: McGraw-Hill. 1958.
R. Elliott, Constitution of Binary Alloys, First Suppl. New York: McGraw-Hill. 1965.
F. A. Shunk, Constitution of Binary Alloys, 2. Suppl. New York: McGraw-Hill. 1969.
P. J. Spencer undF. H. Putland, J. Iron Steel Instit.211, 293 (1973).
Y. Aoki undM. Yamamoto, Phys. stat. sol. (a)22, 131 (1974).
E. R. Stevens undO. N. Carlson, Metallurg. Trans.1, 1267 (1970).
H. Wada, Trans. Iron Steel Inst. Japan.9, 399 (1969).
R. E. Hanneman undA. N. Mariano, Trans. Met. Soc. AIME230, 937 (1964).
W. B. Pearson, Handbook Lattice Spacings and Structures of Metals and Alloys. London: Pergamon Press. 1958.
Author information
Authors and Affiliations
Additional information
Mit 6 Abbildungen
Rights and permissions
About this article
Cite this article
El-Shahat, M.F., Holleck, H. Zum Aufbau der Systeme V—(Fe, Co, Ni)—N. Monatshefte für Chemie 109, 193–201 (1978). https://doi.org/10.1007/BF00911960
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00911960