Monatshefte für Chemie / Chemical Monthly

, Volume 109, Issue 1, pp 165–177 | Cite as

Komplexe von N,N-Di-(β-hydroxyäthyl)-dithiocarbaminat mit Übergangs- und Nachübergangs-Elementen

  • Balachandra G. Sejekan
  • Gopalaswamiengar Aravamudan
Anorganische, Struktur- und Physikalische Chemie

Complexes of N,N-Di-(β-hydroxyethyl)-dithiocarbamate with transition and post transition elements


The complexation tendencies of N,N-di-(β-hydroxyethyl)-dithiocarbamic acid [DEADTCH, (CH2CH2OH)2NCSSH] towards a large number of metal ions have been examined. The complexes formed with transition and post-transition metal ions in slightly acidic and neutral solutions have the general formulaM(DEADTC)x, wherex is the valence state of the metal,M=Cr(III), Fe(III), Co(III), Ni(II), Cu(II), Zn(II), Cd(II), Hg(II), Tl(I), and Tl(III). In addition the interesting mixed ligand complex ClHg(DEADTC) was prepared. These complexes have been characterised through X-ray, magnetic, conductance and spectral (UV and IR) measurements.


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Copyright information

© Springer-Verlag 1978

Authors and Affiliations

  • Balachandra G. Sejekan
    • 1
  • Gopalaswamiengar Aravamudan
    • 1
  1. 1.Department of ChemistryIndian Institute of TechnologyMadrasIndien

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