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Ethynylsilanes in an organosodium synthesis

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of trialkylethynylsilanes with metallic sodium was investigated and it was established that they easily react with the latter forming trialkylsilylsodiumacetylenes.

  2. 2.

    The sodium derivatives of ethylsilanes are more reactive compounds compared to sodiumacetylene and tert-butylsodiumacetylene.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    M. F. Shostakovskii, N. V. Komarov & O. G. Yarosh

Authors
  1. M. F. Shostakovskii
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  2. N. V. Komarov
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  3. O. G. Yarosh
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Additional information

Translated from Ivestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2575–2577, November, 1967.

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Shostakovskii, M.F., Komarov, N.V. & Yarosh, O.G. Ethynylsilanes in an organosodium synthesis. Russ Chem Bull 16, 2458–2459 (1967). https://doi.org/10.1007/BF00911871

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  • DOI: https://doi.org/10.1007/BF00911871

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