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Transformation of polymethylenesilanes under the influence of aluminum chloride

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Dimethylhexamethylenesilane is polymerized under the influence of aluminum chloride with an opening of the ring. Methylethylpentamethylenesilane, isomeric with it, undergoes disproportionation of the alkyl radicals under the same conditions.

  2. 2.

    Dimethylpentamethylenesilane (80% yield) and dimethylhexamethylenesilane (1–3% yield) are formed from α,Ω-bis(trimethylsilyl)penta- and -hexamethylene under the influence of aluminum chloride.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, USSR

    N. S. Nametkin, V. M. Vdovin & K. S. Pushchevaya

Authors
  1. N. S. Nametkin
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  2. V. M. Vdovin
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  3. K. S. Pushchevaya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2537–2542, November, 1967.

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Nametkin, N.S., Vdovin, V.M. & Pushchevaya, K.S. Transformation of polymethylenesilanes under the influence of aluminum chloride. Russ Chem Bull 16, 2413–2417 (1967). https://doi.org/10.1007/BF00911855

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  • DOI: https://doi.org/10.1007/BF00911855

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