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Reactions of alkane acids and their derivatives with 1-alkenes, initiated by tertiary butyl hydroperoxide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The authors have obtained 1∶1 adducts by the addition of acetic anhydride, malonic ester, propionic acid, and methyl monochloroacetate to 1-alkenes in the presence of tert-butyl hydroperoxide.

  2. 2.

    Initiation of addition is due mainly to the free radicals formed by thermal decomposition of tert-butyl peresters and tert-butyl hydroperoxide.

  3. 3.

    tert-Butyl peresters are formed by acylation of tert-butyl hydroperoxide by carboxylic acids, their esters, and anhydrides.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    G. I. Nikishin, Yu. N. Ogibin & I. A. Palanuer

Authors
  1. G. I. Nikishin
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  2. Yu. N. Ogibin
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  3. I. A. Palanuer
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2478–2483, November, 1967.

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Nikishin, G.I., Ogibin, Y.N. & Palanuer, I.A. Reactions of alkane acids and their derivatives with 1-alkenes, initiated by tertiary butyl hydroperoxide. Russ Chem Bull 16, 2360–2364 (1967). https://doi.org/10.1007/BF00911845

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  • DOI: https://doi.org/10.1007/BF00911845

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