Conclusions
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1.
Organomagnesium compounds react with the 2,4,6-tri-tert-butylphenoxyl radical according to a radical type reaction with the formation (after hydrolysis) of 2,4,6-tri-tert-butylphenol and 2, (4)-alkyl-2, 4,6-tri-tert-butylcyclohexadienones.
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2.
A new method of synthesis of gem-dialkylcyclohexadienones is suggested by the reaction of phenoxyl radicals with organomagnesium compounds.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2470–2473, November, 1967.
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Ershov, V.V., Volod'kin, A.A. & Tarkhanova, M.V. Reaction of organomagnesium compounds with 2,4,6-tri-tert-butylphenoxyl. Russ Chem Bull 16, 2352–2354 (1967). https://doi.org/10.1007/BF00911843
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DOI: https://doi.org/10.1007/BF00911843