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Correlation of the nuclear quadrupole resonance frequencies of Cl35 of dihydrochlorides of certain phosphorus acids with the σφ constants of substituents on the phosphorus atom

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Two linear relationships exist between the nuclear quadrupole resonance frequencies of Cl35 in dichlorides of certain phosphorus acids and the σφ constants of substituents at the phosphorus atom; one of them is formed by alkyldichlorophosphonates, while the other is given by compounds in which conjugation is possible between the substituent and the d-orbitals of phosphorus-alkyldichlorophosphates, aryl- and vinyldichlorophosphonates.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    E. N. Tsvetkov, G. K. Semin, T. A. Babushkina, D. I. Lobanov & M. I. Kabachnik

Authors
  1. E. N. Tsvetkov
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  2. G. K. Semin
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  3. T. A. Babushkina
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  4. D. I. Lobanov
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  5. M. I. Kabachnik
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2375–2378, November, 1967.

Some of the substances were synthesized by G. P. Kharitonova, whom the authors would like to thank.

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Tsvetkov, E.N., Semin, G.K., Babushkina, T.A. et al. Correlation of the nuclear quadrupole resonance frequencies of Cl35 of dihydrochlorides of certain phosphorus acids with the σφ constants of substituents on the phosphorus atom. Russ Chem Bull 16, 2267–2270 (1967). https://doi.org/10.1007/BF00911824

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  • DOI: https://doi.org/10.1007/BF00911824

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