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The Influence of oxygen on the electrical properties of ion-radicals of salts of tetracyanoquinodimethane with alkali metals

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    When the anion-radicals of salts of tetracyanoquinodimethane with alkali metals are heated in vacuum, their electrical properties change irreversibly: their electrical conductivity decreases, its activation energy increases, and the sign of the charge carriers changes.

  2. 2.

    The observed changes in the electrical properties are connected with the elimination during the heating process of oxygen dissolved in the sample which plays the part of acceptor impurity.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 659–661, March, 1968.

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Vlasova, R.M., Grishaeva, T.I., Rozenshtein, L.D. et al. The Influence of oxygen on the electrical properties of ion-radicals of salts of tetracyanoquinodimethane with alkali metals. Russ Chem Bull 17, 637–639 (1968). https://doi.org/10.1007/BF00911630

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  • DOI: https://doi.org/10.1007/BF00911630

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