Synthesis and some properties of coordination polymers based on diphenylphosphinic acid

  • V. V. Korshak
  • A. M. Polyakova
  • O. V. Vinogradova
  • K. N. Anisimov
  • N. E. Kolobova
  • M. N. Kotova
Organic and Biological Chemistry
  • 48 Downloads

Conclusions

  1. 1.

    The polycoordination reaction of diphenylphosphinic acid with the metal carbonyls Mn2(CO)10, W(CO)6, Mo(CO)6 and Mn(CH3COO2) gave coordination polymers containing an inorganic backbone chain in the molecule. A linear structure was proposed for these polymers, while a three-dimensional structure was postulated for the polymer obtained from diphenylphosphinic acid and Fe(CO)5.

     
  2. 2.

    Some of the properties of the obtained polymers were studied.

     

Keywords

Polymer Carbonyl Coordination Polymer Linear Structure Backbone Chain 

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Literature cited

  1. 1.
    H. E. Podall and T. L. Iapalucci, J. Polymer Sci.,B, 1, 457 (1963).Google Scholar
  2. 2.
    L. J. Bellamy, Infrared Spectra of Complex Molecules [Russian translation], IL (1963).Google Scholar
  3. 3.
    E. M. Popov, M. I. Kabachnik, and L. S. Mayants, Usp. Khim.,30, 846 (1961).Google Scholar
  4. 4.
    W. A. Higgins, P. W. Vogel, and W. G. Craig, J. Am. Chem. Soc,77, 1864 (1955).Google Scholar

Copyright information

© Consultants Bureau 1968

Authors and Affiliations

  • V. V. Korshak
    • 1
  • A. M. Polyakova
    • 1
  • O. V. Vinogradova
    • 1
  • K. N. Anisimov
    • 1
  • N. E. Kolobova
    • 1
  • M. N. Kotova
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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