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Preparation of phosphorylated chloral hemiacetals, their properties and reactions

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Reactions of chloral hemiacetals with dialkyl phosphorochloridites were studied. They lead in high yields to phosphorylated chloral hemiacetals containing tervalent phosphorus.

  2. 2.

    By the addition of sulfur and by oxidation the corresponding phosphorothioates and phosphates were obtained.

  3. 3.

    The reactions of 1-alkoxy-2,2,2-trichloroethyl dialkyl phosphites with benzyl chloride and with acetyl chloride and chloral take different courses. Possible mechanisms for these reactions are proposed.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR

    K. V. Nikonorov, É. A. Gurylev, R. R. Shagidullin & A. V. Chernova

Authors
  1. K. V. Nikonorov
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  2. É. A. Gurylev
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  3. R. R. Shagidullin
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  4. A. V. Chernova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 593–602, March, 1968.

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Nikonorov, K.V., Gurylev, É.A., Shagidullin, R.R. et al. Preparation of phosphorylated chloral hemiacetals, their properties and reactions. Russ Chem Bull 17, 574–581 (1968). https://doi.org/10.1007/BF00911614

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  • DOI: https://doi.org/10.1007/BF00911614

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