Conclusions
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1.
Mono(cyclopentadienyl)alkoxytitanium halides were synthesized by reverse disproportionation reactions.
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2.
The preparation of pentamethylcyclopentadienylethoxytitanium chlorides is described, along with the synthesis of pentamethylcyclopentadienyl(cyclopentadienyl)titanium dichloride. The latter compound is the first bis(cyclopentadienyl) derivative of titanium known to contain a completely substituted cyclopentadienyl ring.
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3.
The IR spectra of the compounds were studied.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 527–534, March, 1968.
The spectra of the first six compounds were taken by G. G. Dvoryantsevaya of the Institute of the Chemistry of Natural Compounds, Academy of Sciences of the USSR. The remaining spectra were taken by B. V. Lokshinyi. The authors deeply appreciate their help.
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Nesmeyanov, A.N., Nogina, O.V. & Dubovitskii, V.A. Mono(cyclopentadienyl)alkoxytitanium halides. Russ Chem Bull 17, 514–520 (1968). https://doi.org/10.1007/BF00911602
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DOI: https://doi.org/10.1007/BF00911602