Conclusions
-
1.
The rate constant of the reaction of atomic hydrogen with ethane was determined by measuring the first limits of ignition of hydrogen-oxygen mixtures, containing small additions of ethane.
-
2.
From the same data we determined the rate constant of the reaction H+O2=OH+O, the value of which is in good agreement with the literature data.
Similar content being viewed by others
Literature cited
N. N. Tikhomirova and V. V. Voevodskii, Chain Reactions of Oxidation of Hydrocarbons in the Gas Phase [in Russian], Izd-vo AN SSSR (1955), p. 172; N. N. Tikhomirova, Dissertation [in Russian], Moscow State University (1951).
R. R. Baldwin, N. S. Corney, and R. F. Simmons, Nature,169, 201 (1952); R. R. Baldwin and R. F. Simmons, Trans. Faraday Soc.,53, 955 (1964).
V. Lewis and G. Elbe, Combustion, Flames, and Explosions in Gases [Russian translation], Izd-vo AN SSSR (1948).
N. N. Semenov, Some Problems of Chemical Kinetics and Reactivity [in Russian], Izd-vo AN SSSR (1958).
V. V. Azatyan, Dissertation [in Russian], Moscow (1963).
A. B. Nalbandyan and V. V. Voevodskii, Mechanism of the Oxidation and Combustion of Hydrogen [in Russian], Izd-vo AN SSSR, Moscow-Leningrad (1948).
N. I. Gorban'i and A. B. Nalbandyan, Zh. Fiz. Khimii,36, 1757 (1962).
V. V. Voevodskii and V. N. Kondrat'ev, Progress in Reaction Kinetics,1, 43 (1961).
V. V. Azatyan, Arm. Khim. Zh.,20, 577 (1967).
R. R. Baldwin and A. Melvine, J. Chem. Soc., 1785 (1964).
V. N. Kondrat'ev, Kinetics of Chemical Gas Reactions [in Russian], Izd-vo AN SSSR (1958).
F. Kaufman and F. P. Del-Greco, Eleventh Symposium on Combustion and Flame, New York, 659 (1962).
M. A. A. Klyne and B. A. Thrush, Proc. Roy. Soc.,A-275, 544 (1963).
E. L. Wong and A. E. Potter, J. Chem. Phys.,43, 3371 (1965).
V. V. Azatyan, L. B. Romanovich, and S. G. Sysoeva, Fizika Goreniya i Vzryva,3, 79 (1967); V. V. Azatyan, V. V. Voevodskii, and A. B. Nalbandyan, Kinetika i Kataliz,2, 342 (1961); V. V. Azatyan and A. B. Nalbandyan, Zh. Vses. Khim. O-va im. D. I. Mendeleeva, 162 (1966).
J. H. Knox and C. H. J. Wells, Trans. Faraday Soc.,59, 2786 (1963); R. R. Baldwin, Zh. Vses. Khim. O-va im. D. I. Mendeleeva,60, 527 (1964).
R. R. Baldwin and R. W. Walker, Trans. Faraday Soc.,60, 1236 (1964).
N. N. Semenov, Chain Reactions [in Russian], Goskhimizdat, Moscow-Leningrad (1934).
S. Chapman and G. Kauling, Mathematical Theory of Inhomogeneous Gases [Russian translation], Izd-vo AN SSSR (1960).
G. L. Schott and I. L. Kinsey, J. Chem. Phys.,29, 1177 (1958).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 496–500, March, 1968.
Rights and permissions
About this article
Cite this article
Parsamyan, N.I., Arakelyan, É.A., Azatyan, V.V. et al. Study of the reaction of atomic hydrogen with ethane. Russ Chem Bull 17, 486–490 (1968). https://doi.org/10.1007/BF00911596
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00911596