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Tautomerism and geometric isomerism of nitrogen-containing derivatives of carbonyl compounds

Communication 5. Polarographic study of semicarbazones and thiosemicarbazones of aromatic aldehydes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A study was made of the polarographic behavior of the semicarbazones and thiosemicarbazones of benzaldehyde, p-isopropylbenzaldehyde, p-dimethyl-aminobenzaldehyde, salicyladehyde, and o-, m-, and p-nitrobenzaldehydes. and it was shown that two electrons take part in their reduction.

  2. 2.

    The effect of the structures of semicarbazones and thiosemicarbazones on the ease of reduction at a dropping mercury electrode is explained from the point of view of modern concepts on the structure of organic compounds.

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Literature cited

  1. Yu.P. Kitaev, G.K. Budnikov and A.E. Arbuzov, Izv. AN SSSR. Otd. khim. n.1961, 824.

  2. Yu.P. Kitaev, G.K. Budnikov and A.E. Arbuzov, Izv. AN SSSR. Otd. khim. n.1961, 1222.

  3. Yu. P. Kitaev and G.K. Budnikov, Abstracts of Papers Read at the Third Conference on the Electrochemistry of Organic Compounds [in Russian] (Moscow, 1960).

  4. H.W. Nürnberg, Angew. Chemie72, 433 (1960).

    Google Scholar 

  5. F. Mietzsch, Chem. Abstrs49, 6997 (1955).

    Google Scholar 

  6. A.G. Stromberg and G.M. Markacheva, Zh. fiz. khirnii28, 671 (1954).

    Google Scholar 

  7. G. Cilento, J. Amer. Chem. Soc.71, 1112 (1949).

    Google Scholar 

  8. R. Brockman and D. Pearson, J. Amer. Chem. Soc.74, 4128 (1952).

    Google Scholar 

  9. J. Tirouflet, Bull. Soc, chim France1956, 274.

  10. P. Zuman, Coll. Czechoslov. Chem. Communs19, 599 (1954).

    Google Scholar 

  11. L.P. Hammett, Physical Organic Chemistry, McGraw-Hill, N.Y., 1940.

    Google Scholar 

  12. H.H. Jaffe, Chem. Revs53, 191 (1953).

    Google Scholar 

  13. P. Zuman, Coll. Czechoslov. Chem. Communs25, 3025 (1960).

    Google Scholar 

  14. Yu.P. Kitaev, G.K. Budnikov, T.V. Troepol'skaya and A.E. Arbuzov, Dokl. AN SSSR,137, 862 (1961).

    Google Scholar 

  15. Dictionary of Organic Compounds [Russian translation] (IL, Moscow, 1949).

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Authors and Affiliations

  1. A.E. Arbuzov Chemical Institute, Kazan' Branch, Academy of Sciences, USSR

    Yu. P. Kitaev, G. K. Budnikov & A. E. Arbuzov

Authors
  1. Yu. P. Kitaev
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  2. G. K. Budnikov
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  3. A. E. Arbuzov
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Kitaev, Y.P., Budnikov, G.K. & Arbuzov, A.E. Tautomerism and geometric isomerism of nitrogen-containing derivatives of carbonyl compounds. Russ Chem Bull 10, 1652–1658 (1961). https://doi.org/10.1007/BF00911433

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  • DOI: https://doi.org/10.1007/BF00911433

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