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Reaction of vinyl ethers with furan and with 2-methylfuran

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The reaction of vinyl ethers with furan and with 2-methylfuran was studied under conditions under which vinyl ethers undergo diene condensation and also in presence of acid catalysts.

  2. 2.

    Under diene-synthesis conditions vinyl ethers do not react with furan and with 2-methylfuran, but in presence of acid catalysts substitutive addition occurs, leading to the addition of two molecules of 2-methylfuran or furan to the vinyl ether molecule and formation of 2,2′-ethylidenebis(5-methylfuran) and 2,2′-ethylidenedifuran.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    M. F. Shostakovskii, A. V. Bogdanova & A. N. Volkov

Authors
  1. M. F. Shostakovskii
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  2. A. V. Bogdanova
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  3. A. N. Volkov
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Shostakovskii, M.F., Bogdanova, A.V. & Volkov, A.N. Reaction of vinyl ethers with furan and with 2-methylfuran. Russ Chem Bull 11, 2125–2127 (1962). https://doi.org/10.1007/BF00911377

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  • DOI: https://doi.org/10.1007/BF00911377

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