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Vinyl ethers Communication 7. Ion- and radical-induced homo- and co-polymerization of vinyl ethers of cyclohexanol,decahydro-2-naphthol, and 2-naphthol

  • A. V. Bogdanova
  • M. F. Shostakovskii
  • G. K. Krasil'nikova
Article
  • 24 Downloads

Summary

  1. 1.

    A study was made of the homo- and co-polymerization of cyclohexyl, decahydro-2-naphthyl, and 2-naphthyl vinyl ethers by ionic and free-radical mechanisms.

     
  2. 2.

    Conditions were found for the preparation in good yield of polymers of cyclohexyl, decahydro-2-naphthyl, and 2- naphthyl vinyl ethers and of their copolymers with ethyl, butyl, and phenyl vinyl ethers in presence of the BF3-ether complex. Most of these polymers were solids.

     
  3. 3.

    The polymerization of cyclohexyl, decahydro-2-naphthyl, and 2-naphthyl vinyl ethers in presence of benzoyl peroxide or 2,2′-azobis[2-methylpropionitrile] requires a large amount (up to 6%) of initiator, the application of heat, and prolonged treatment, and the yields of polymers are low.

     
  4. 4.

    In presence of benzoyl peroxide, cyclohexyl, decahydro-2-naphthyl, and phenyl vinyl ethers can be brought into copolymerization with the methyl esters of acrylic and methacrylic acids; depending on the relative amounts of the monomers taken, copolymers of various compositions are formed with vinyl ether contents of up to 44%.

     

Keywords

Methyl Ester Butyl Benzoyl Benzoyl Peroxide Methacrylic Acid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. [1]
    M. F. Shostakovskii and A. V. Bogdanova, J. Gen. Chem. 20, 1337 (1950).Google Scholar
  2. [2]
    M. F. Shostakovskii and A. V. Bogdanova, Bull. Acad. Sci. USSR, Div. Chem. Sci. (1954), 911.Google Scholar
  3. [3]
    M. F. Shostakovskii and A. V. Bogdanova, J. Gen. Chem. 25, 1550 (1955).Google Scholar
  4. [4]
    V. M. Isaguliants, N. A. Medzykhovskaia, and V. P. Shishkov, Proc. Acad. Sci. USSR 85, 506, 567 (1952).Google Scholar
  5. [5]
    W. Reppe, Acetylene Chemistry (New York, 1949), p. 39.Google Scholar
  6. [6]
    J. Copenhaver and M. Bigelow, Acetylene and Carbon Monoxide Chemistry, Reinhold Publ. Corp. 4 (1949), 32–118.Google Scholar
  7. [7]
    M. F. Shostakovskii, B. I. Mikhant'ev, and N. N. Ovchinnikova, Bull. Acad. Sci. USSR, Div. Chem. Sci. (1953), 1056.Google Scholar
  8. [8]
    M. F. Shostakovskii and A. V. Bogdanova, Bull. Acad. Sci. USSR, Div. Chem. Sci. (1954), 919.Google Scholar
  9. [9]
    M. F. Shostakovskii and F. P. Sidel'kovskaia, Bull. Acad. Sci. USSR, Div. Chem. Sci. (1955), 1085.Google Scholar
  10. [10]
    M. F. Shostakovskii and A. M. Khomutov. Bull. Acad. Sci. USSR, Div. Chem. Sci. (1954), 924.Google Scholar

Copyright information

© Consultants Bureau Inc. 1959

Authors and Affiliations

  • A. V. Bogdanova
    • 1
  • M. F. Shostakovskii
    • 1
  • G. K. Krasil'nikova
    • 1
  1. 1.N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSRUSSR

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