Vinyl ethers Communication 7. Ion- and radical-induced homo- and co-polymerization of vinyl ethers of cyclohexanol,decahydro-2-naphthol, and 2-naphthol

  • A. V. Bogdanova
  • M. F. Shostakovskii
  • G. K. Krasil'nikova
Article
  • 22 Downloads

Summary

  1. 1.

    A study was made of the homo- and co-polymerization of cyclohexyl, decahydro-2-naphthyl, and 2-naphthyl vinyl ethers by ionic and free-radical mechanisms.

     
  2. 2.

    Conditions were found for the preparation in good yield of polymers of cyclohexyl, decahydro-2-naphthyl, and 2- naphthyl vinyl ethers and of their copolymers with ethyl, butyl, and phenyl vinyl ethers in presence of the BF3-ether complex. Most of these polymers were solids.

     
  3. 3.

    The polymerization of cyclohexyl, decahydro-2-naphthyl, and 2-naphthyl vinyl ethers in presence of benzoyl peroxide or 2,2′-azobis[2-methylpropionitrile] requires a large amount (up to 6%) of initiator, the application of heat, and prolonged treatment, and the yields of polymers are low.

     
  4. 4.

    In presence of benzoyl peroxide, cyclohexyl, decahydro-2-naphthyl, and phenyl vinyl ethers can be brought into copolymerization with the methyl esters of acrylic and methacrylic acids; depending on the relative amounts of the monomers taken, copolymers of various compositions are formed with vinyl ether contents of up to 44%.

     

Keywords

Methyl Ester Butyl Benzoyl Benzoyl Peroxide Methacrylic Acid 

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Copyright information

© Consultants Bureau Inc. 1959

Authors and Affiliations

  • A. V. Bogdanova
    • 1
  • M. F. Shostakovskii
    • 1
  • G. K. Krasil'nikova
    • 1
  1. 1.N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSRUSSR

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