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Reverse-disproportionation reaction of chelate zirconium compounds

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    By reaction ofβ-diketones with zirconyl nitrate, zirconium bisacetylacetonate dinitrate and zirconium bisbenzoylacetonate were prepared.

  2. 2.

    By reaction ofβ-diketones with zirconyl nitrate in presence of sodium bicarbonate, zirconium trisacetylacetonate nitrate and zirconium trisbenzoylacetonate nitrate were prepared.

  3. 3.

    The reverse-disproportionation reaction is applicable to chelate zirconium compounds. Reaction of zirconium tetrakisacetylacetonate and of zirconium tetrakisbenzoylacetonate with the corresponding dinitrates gave the zirconium trisacylacetonate mononitrates.

  4. 4.

    The above-mentioned mono- and di-nitrates give double compounds with benzene and dioxane.

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Literature cited

  1. R. Kh. Freidlina, E. M. Brainina, and A. N. Nesmeianov, Bull, Acad. Sci. USSR, Div. Chem. Sci. (1957), p. 36.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, USSR

    E. M. Brainina, R. Kh. Freidlina & A. N. Nesmeianov

Authors
  1. E. M. Brainina
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  2. R. Kh. Freidlina
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  3. A. N. Nesmeianov
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Brainina, E.M., Freidlina, R.K. & Nesmeianov, A.N. Reverse-disproportionation reaction of chelate zirconium compounds. Russ Chem Bull 7, 910–913 (1958). https://doi.org/10.1007/BF00911339

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  • DOI: https://doi.org/10.1007/BF00911339

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