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Beiträge zur Chemie der Pyrrolpigmente, 1. Mitt.: Der induzierte Circulardichroismus einiger Pyrromethenderivate in cholesterischer Mesophase

On the chemistry of pyrrole pigments, I.: The cholesteric mesophase-induced circular dichroism of some dipyrromethene derivatives

  • Organische Chemie und Biochemie
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Abstract

The electron absorption spectra of some symmetrically substituted alkyl-dipyrromethene derivatives were analyzed by means of a liquid-crystal-induced circular dichroism technique. The “main band” (440 nm) was found to be polarized parallel, whereas all short-wavelength bands (including one hidden by the main band) are polarized perpendicular to the “long” axis of the molecule.

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Literatur

  1. z. B.:S. B. Hendricks undH. W. Siegelman in Comprehensive Biochemistry (M. Florkin undE. H. Stotz, Hrsg.), Vol.27, S. 211. Elsevier. 1967;H. Smith, Nature227, 665 (1970);H. Mohr, Lectures on Photomorphogenesis. Springer. 1972;R. E. Kendrick undC. J. P. Spruit, Photochem. Photobiol.18, 139, 145 und 153 (1973).

  2. z. B.:R. K. Clayton, Light and Living Matter, Bd.2, S. 160. McGraw-Hill. 1971;W. Rüdiger, Fortschr. Chem. org. Naturst.29, 60 (1971).

    Google Scholar 

  3. Siehe z. B.:C. Weiss, Jr., J. Mol. Spect.44, 37 (1972).

    Google Scholar 

  4. F. Pruckner undA. Stern, Z. Physikal. Chem.A 180, 25 (1937);R. W. Guy undR. A. Jones, Austral. J. Chem.18, 363 (1965).

    Google Scholar 

  5. R. A. Levenson, H. B. Gray undG. P. Ceasar, J. Amer. Chem. Soc.92, 3653 (1970);F. D. Saeva, J. Amer. Chem. Soc.94, 5135 (1972).

    Google Scholar 

  6. E. Sackmann undJ. Voss, Chem. Phys. Lett.14, 528 (1972);E. Sackmann undH. Möhwald, J. Chem. Phys.58, 5407 (1973).

    Google Scholar 

  7. S. F. Mason undR. D. Peacock, Chem. Phys. Lett.21, 406 (1973) und J. Chem. Soc. Chem. Commun.1973, 712.

    Google Scholar 

  8. M. Elder undB. R. Penfold, J. Chem. Soc.A 1969, 2556;F. C. March, D. A. Couch, K. Emerson, J. E. Ferguson undW. T. Robinson, J. Chem. Soc.A 1971, 440.

  9. Darstellung von 1,2,3,6,7,8-Hexahydropyren: soll vonH. L. in anderem Zusammenhange mitgeteilt werden.

  10. H. Fischer, P. Halbig undB. Walach, Ann. Chem.452, 268 (1927).

    Google Scholar 

  11. Vgl. hiezu z. B. die Deprotonierung von Corrinderivaten:H. U. Blaser, Diss. Nr. 4662, ETH-Zürich,1971, 75.

  12. J. Löliger undR. Scheffold, J. Chem. Educ.49, 646 (1972).

    Google Scholar 

  13. F. Bell undD. H. Waring, J. Chem. Soc.1949, 267.

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Falk, H., Hofer, O. & Lehner, H. Beiträge zur Chemie der Pyrrolpigmente, 1. Mitt.: Der induzierte Circulardichroismus einiger Pyrromethenderivate in cholesterischer Mesophase. Monatshefte für Chemie 105, 169–178 (1974). https://doi.org/10.1007/BF00911302

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  • DOI: https://doi.org/10.1007/BF00911302

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