Abstract
In continuation of earlier investigations, a series of compounds were isolated from a distillate fraction of a shale oil raffinate after the application of various chromatographic procedures, and characterized by spectroscopic methods.
The following compound types are arranged in order of their abundance: 2,2′-dithienyls, 2-phenylthiophenes, thionaphthenes, thiophenes, dithienylmethanes,-ethanes and-propanes, naphthalenes, benzenes, alkanes, alkenes, thiophthenes, diphenyls, fluorenes, tricyclic aromatics, tricyclic sulphur and oxygen heterocycles. The aromatic ring systems were almost invariably alkyl substituted.
Zusammenfassung
Im Anschluß an frühere Untersuchungen konnte aus einer Siedefraktion eines Schieferölraffinates nach Anwendung verschiedener chromatographischer Verfahren eine Reihe von Verbindungen isoliert und mit spektroskopischen Methoden charakterisiert werden.
Die nachfolgende Aufzählung der Verbindungsklassen erfolgt in der Reihenfolge ihres mengenmäßigen Vorkommens: 2,2′-Dithienyle, 2-Phenylthiophene, Thionaphthene, Thiophene, Dithienyl-methane,-äthane und-propane, Naphthaline, Benzole, Alkane, Alkene, Thiophthene, Diphenyle, Fluorene, tricyclische Aromaten, sowie tricyclische Schwefel-und Sauerstoffheteroaromaten. Die aromatischen Ringsysteme waren fast ausschließlich alkylsubstituiert.
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Herrn Prof. Dr.K. Jentsch mit den besten Wünschen zum 60. Geburtstag gewidmet.
4. Mitt.:M. Pailer undH. Begutter
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Pailer, M., Grünhaus, H. Untersuchung stark schwefelhältiger Schieferöle, 5. Mitt.. Monatshefte für Chemie 104, 312–337 (1973). https://doi.org/10.1007/BF00911172
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DOI: https://doi.org/10.1007/BF00911172