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IR-Spektren einiger hydratisierter Fluoro-aluminate,-gallate und-indate

Fluoro metallates (III), IV: IR-Spectra of some hydrated fluoro-aluminates,-gallates, and-indates

Untersuchungen über Fluoro-metallate (III), 4. Mitt.

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Abstract

Interpretation of the IR spectra of several compounds of the stoichiometryM 2 I M IIIF5·H2O,M I M IIIF4·2H2O and their deuterated analogs proves the presence of the lattice water. Hydrogen bond is stronger in the case of fluorogallates in comparision to the similar fluoroaluminates and indates.

Zusammenfassung

Die Analyse der IR-Spektren einer Auswahl der Verbindungen des TypsM 2 I M IIIF5·H2O bzw.M I M IIIF4·2 H2O und der entsprechenden Deuterohydrate führt zum Ergebnis, daß das Wasser nicht koordinativ gebunden, sondern als Gitterwasser auftritt. Bei den hydratisierten Fluorogallaten ist die Wasserstoffbindung stärker ausgeprägt als bei den entsprechenden Fluoro-aluminaten und-indaten.

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Authors and Affiliations

  1. Laboratorium für anorganische Chemie und Institut „Jožef Stefan”, Universität Ljubljana, Jugoslawien

    P. Bukovec, B. Orel & J. Šiftar

Authors
  1. P. Bukovec
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  2. B. Orel
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  3. J. Šiftar
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Additional information

3. Mitt.: Mh. Chem.102, 885 (1971).

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Bukovec, P., Orel, B. & Šiftar, J. IR-Spektren einiger hydratisierter Fluoro-aluminate,-gallate und-indate. Monatshefte für Chemie 104, 194–199 (1973). https://doi.org/10.1007/BF00911160

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  • DOI: https://doi.org/10.1007/BF00911160

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