Monatshefte für Chemie / Chemical Monthly

, Volume 110, Issue 5, pp 1233–1236 | Cite as

Synthese und Reaktionen desDiels-Alder-Addukts aus Pyren und Hexachlorcyclopentadien

  • Gerd-Peter Blümer
  • Maximilian Zander
Organische Chemie und Biochemie

Synthesis and reactions of the diels-alder-adduct from pyrene and hexachlorocyclopentadiene


TheDiels-Alder adduct2 from pyrene and hexachlorocyclopentadiene exhibits a different substitution pattern than pyrene itself, namely that of phenanthrene. By reactions with the adduct following Retro-Diels-Alder splitting, pyrene substitution products are accessible that cannot be obtained by direct substitution of pyrene. This is demonstrated by the synthesis of 4-chloropyrene (5) and 4-bromopyrene (6).


Diels Alder reaction 4-Halo-pyrenes Pyrene 


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Copyright information

© Springer-Verlag 1979

Authors and Affiliations

  • Gerd-Peter Blümer
    • 1
  • Maximilian Zander
    • 1
  1. 1.Laboratorium der Rütgerswerke AGCastrop-Rauxel

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