Catalytic polymerization of olefins

Communication 7. Polymerization of ethylene over a nickelous oxide — aluminum silicate catalyst
  • Ya. T. Eidus
  • N. I. Ershov
  • K. V. Puzitskii
  • B. A. Kazanskii
Article
  • 22 Downloads

Summary

  1. 1.

    Nickelous oxide — synthetic aluminum silicate (tablet form) catalysts prepared by precipitation or impregnation show considerable activity for the polymerization of ethylene at 300° and atmospheric pressure. Aluminum silicate is not itself a catalyst in this reaction.

     
  2. 2.

    When nickel is replaced by iron, cobalt, or copper in a nickelous oxide — aluminum silicate catalyst, the products are inactive for the polymerization of ethylene.

     
  3. 3.

    Aluminum silicate that has been treated with a solution of alkali is unsuitable as a carrier for nickelous oxide; this is in good agreement with the view of the activity of hydrogen ions in an aluminum silicate.

     

Keywords

Oxide Hydrogen Iron Polymerization Copper 

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Literature cited

  1. 1.
    Ya.T. Éidus, K.V. Puzitskii, and B.A. Kazanskii, Izvest. Akad. Nauk, 115 (1960).Google Scholar
  2. 2.
    J.P. Hogan, R.L. Banks, W.C. Lanning, and A. Clark, Ind. Eng. Chem.47, 752 (1955).Google Scholar
  3. 3.
    L.I. Piguzova, Khim. i Tekhnol. Topliv i Masel6, 43 (1956).Google Scholar
  4. 4.
    B.A. Kazanskii, Ya.T. Éidus, K.V. Puzitskii, and N.I. Ershov, Investigation of the Catalystic Polymerization and Hydropolymerization of Ethylene and its Hydrocondensation with Carbon Monoxide [in Russian] (Izd. AN SSSR, Moscow, 1955).Google Scholar
  5. 5.
    Ya.T. Éidus, K.V. Puzitskii, N.I. Ershov, and B.A. Kazanskii, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk, 111 (1960).Google Scholar
  6. 6.
    F.H. Gayer, Ind. Eng. Chem.25, 122 (1933).Google Scholar
  7. 7.
    Ya.T. Éidus and I.V. Guseva, Izvest. Akad. Nauk SSSR, Otdel. Khim. Nauk, 2195 (1959).Google Scholar
  8. 8.
    H.A. Cheney, S.H. McAllister, E.B. Fountain, J. Anderson, and W.M. Peterson, Ind. Eng. Chem.42, 2580 (1950).Google Scholar

Copyright information

© Consultants Bureau Enterprises, Inc. 1961

Authors and Affiliations

  • Ya. T. Eidus
    • 1
  • N. I. Ershov
    • 1
  • K. V. Puzitskii
    • 1
  • B. A. Kazanskii
    • 1
  1. 1.N.D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

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