Combination dispersion [raman] spectra of certain benzene-series hydrocarbons with one or two side chains

  • V. T. Aleksanyan
  • Kh. E. Sterin
  • S. A. Ukholin
  • O. V. Bragin
  • A. L. Liberman
  • E. A. Mikhailova
  • É. N. Smirnova
  • N. I. Tyun'kina
  • B. A. Kazanskii
Inorganic and Analytical Chemistry
  • 14 Downloads

Summary

  1. 1.

    The characteristic group spectral criteria established previously for benzenes with one side chain have been confirmed, and the possibility of distinguishing primary and secondary radicals has been demonstrated.

     
  2. 2.

    The line ≈645 cm−1 is the most characteristic group criterion for 1,4-dialkylbenzenes.

     
  3. 3.

    The existing group criteria for 1,3-dialkylbenzenes were found to be insufficiently characterisitic.

     

Keywords

Benzene Hydrocarbon Characteristic Group Group Criterion Secondary Radical 

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Literature cited

  1. 1.
    B. A. Kazanskii, G. S. Landsberg, V. T. Aleksanyan, T. F. Bulanova, A. L. Liberman, E. A. Mikhailova, A. F. Plate, Kh. E. Sterin, and S. A. Ukholin, Izv. AN SSSR, seriya fiz.18, 704 (1954); Izv. AN SSSR, Old. Khim. n. 1612 (1959).Google Scholar
  2. 2.
    G. S. Landsberg, B. A. Kazanskii, P. A. Bazhulin, T. F. Bulanova, A. L. Liberman, E, A. Mikhailova, A. F. Plate, Kh. E. Sterin, M. M. Sushchinskii, G, A. Tarasova, and S. A. Ukholin, “Determination of individual hydrocarbon composition of straight-run gasolines by the combination [Raman] method” [in Russian] (Acad. Sci. USSR Press, Moscow, 1959).Google Scholar
  3. 3.
    M. R. Fenske, W. G. Braun, R. V. Wiegand, D. Quiggle, R. H. McCormick, and D. H. Rank. Analyt. Chem.19, 700 (1947); W. G. Braun, D. F. Spooner, and M. R. Fenske, Analyt. Chem.22, 1074 (1950).Google Scholar
  4. 4.
    V. T. Aleksanyan, Kh. E. Sterin, A. L. Liberman, E. A. Mikhailova, M. A. Pryanishnikova, and B. A. Kazanskii, Izv. AN SSSR, seriya fiz.19, 225 (1955).Google Scholar
  5. 5.
    G. S. Landsberg, P. A. Bazhulin, and M. M. Suchchinskii, “Basic parameters of combination scattering [Raman] spectra of hydrocarbons” [in Russian] (Acad. Sci. USSR Press, Moscow, 1956).Google Scholar
  6. 6.
    V. T. Aleksanyan and Kh. E. Sterin, Optika i Spectroskopiya_ 2562 (1957).Google Scholar
  7. 7.
    A. L. Liberman, O. V. Bragin, and B. A. Kazanskii, Izv. AN SSSR, Otd. Khim. n. 879 (1959).Google Scholar
  8. 8.
    F. D. Rossini et al., Selected Values of Physical and Thermodynamic Properties of Hydrocarbons and Related Compounds, Pittsburgh, Penn. (1953).Google Scholar
  9. 9.
    H. P. Kaufmann, Fette and Seifen,47, 4 (1940).Google Scholar
  10. 10.
    A. J. Streiff, L. H. Schultz, A. R. Hulme, J. A. Tucker, N. C. Krouskop, and F. D. Rossini, Analyt. Chem.29, 361 (1957).Google Scholar
  11. 11.
    G. Egloff, Physical Constants of Hydrocarbons, New York 3, p. 265.Google Scholar
  12. 12.
    C. M. Buess, J. V. Karabinos, P. V. Kunz, and L. C. Gibbons, Chem. Abstrs.41, 4113 (1947).Google Scholar
  13. 13.
    B. A. Kazanskii, A. L. Liberman, A. F. Platé, M. I. Rozengart, and O. D. Sterligov, Dokl. AN SSSR,71, 477 (1950).Google Scholar
  14. 14.
    G. H. Hennion and L. A. Auspos, J. Am. Chem. Soc.65, 1603 (1943).Google Scholar
  15. 15.
    J. Goubeau, Ber.75, 65 (1942).Google Scholar
  16. 16.
    M. Harrand and C. Bazin, J. phys. radium,18, 687 (1957).Google Scholar

Copyright information

© Consultants Bureau 1962

Authors and Affiliations

  • V. T. Aleksanyan
    • 1
    • 2
  • Kh. E. Sterin
    • 1
    • 2
  • S. A. Ukholin
    • 1
    • 2
  • O. V. Bragin
    • 1
    • 2
  • A. L. Liberman
    • 1
    • 2
  • E. A. Mikhailova
    • 1
    • 2
  • É. N. Smirnova
    • 1
    • 2
  • N. I. Tyun'kina
    • 1
    • 2
  • B. A. Kazanskii
    • 1
    • 2
  1. 1.Commission on SpectroscopyAcademy of SciencesUSSR
  2. 2.N. D. Zelinskii Institute of Organic ChemistryAcademy of SciencesUSSR

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