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Darstellung, Struktur und Reaktionsfähigkeit einiger Metall(I)- und-(II)-Derivate des Diäthylphosphono-Acetons

Synthesis, structure and reactivity of some metal(I and II)-derivatives of diethylphosphono-acetone

  • Anorganische, Struktur- und Physikalische Chemie
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Abstract

Metalation of diethylphosphono-acetone (DÄPA) with potassium or lithium in benzene and with KNH2, LiNH2, or calcium in liquid ammonia afforded the metal derivatives ofDEPA, which were isolated in a pure state. Their structure has been investigated by i.r.- and1H n.m.r.-spectroscopy. In solution metallotropic conversion of thecis-enolate chelates intotrans-enolates and C-forms occurs. The reactivity of these metal derivatives towards some alkylating and acylating reagents as well towards carbonyl compounds has been investigated.

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Authors and Affiliations

  1. Chemischen Fakultät der Universität Sofia, Lehrstuhl für organische Chemie, Sofia, Bulgarien

    G. Petrov, I. Velinov & M. Kirilov

Authors
  1. G. Petrov
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  2. I. Velinov
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  3. M. Kirilov
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Diese Mitteilung ist z. T. Inhalt der Diplomarbeit vonI. Velinov, Univ. Sofia (1968).

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Petrov, G., Velinov, I. & Kirilov, M. Darstellung, Struktur und Reaktionsfähigkeit einiger Metall(I)- und-(II)-Derivate des Diäthylphosphono-Acetons. Monatshefte für Chemie 104, 1301–1306 (1973). https://doi.org/10.1007/BF00910045

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  • DOI: https://doi.org/10.1007/BF00910045

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