Monatshefte für Chemie / Chemical Monthly

, Volume 104, Issue 5, pp 1231–1239 | Cite as

Kinetik und Mechanismus der Substitutionsreaktionen von Komplexverbindungen, 47. Mitt.: Aquationskinetik descis-[Co(en)2Cl (m-Toluidin)]2+ in sauren Lösungen

  • Cs. Várhelyi
  • J. Zsakó
  • A. Ionuţ
Anorganische, Struktur- und Physikalische Chemie

Kinetics and mechanism of substitution reactions of complexes XLVII: Aquation kinetics of cis-[Co(en)2Cl (m-toluidine)]2+ in acid solutions

Abstract

The complex salt [Co(en)2Cl(m-toluidine)](NO3)2 has been synthesized and itscis configuration has been proved on the basis of i.r. spectra. The aquation kinetics of the complex ion has been studied at 4 temperatures in the presence of various amounts of perchloric acid. Experimental data are explained by assuming the following reaction scheme: the amino complex (I) is in equilibrium with its conjugated base, i.e. with the amido-complex (II). The equilibrium constant seems to be of the order of magnitude of 10−3. Both forms of the complex ion participate to aquation reactions. For the amino-form an activation energy of ΔH=25.6 kcal/mole and for the amido-form ΔH=20.4 kcal/mole have been found. These data are compared to the kinetic parameters of the aquation reaction of analogous complexes, and they are discussed, by presuming a dissociation mechanism.

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Copyright information

© Springer-Verlag 1973

Authors and Affiliations

  • Cs. Várhelyi
    • 1
  • J. Zsakó
    • 1
  • A. Ionuţ
    • 1
  1. 1.Chemischen Fakultät der „Babeş-Bolyai”-Universität ClujRumänien

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