Skip to main content
SpringerLink
Log in

Studies on the reaction of salicylidenebenzoic-hydrazide (SBH) with Ce3+, Th4+ and UO2 2+

Komplexe vonCe 3+,Th 4+, undUO 2 2+ mit dem Kondensationsprodukt aus Salicylaldehyd-Benzhydrazid (SBH)

  • Anorganische und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The stoichiometry and structure of salicylidenebenzoic-hydrazine (SBH) chelates with UO2(II), Ce(III) and Th(IV) in buffer-ethanol mixtures and in pure ethanol is studied applying conductometric titration, visible spectrophotometry and ir-spectrophotometry. The ir-spectra revealed that coordination takes place through the C=O and C=N groups.

Zusammenfassung

Die Stöchiometrie und die Struktur derSBH-Me(x) Chelate in Puffer-Ethanol-Mischungen und in reinem Ethanol wurde mittels Leitfähigkeitsmessungen, UV- und IR-Spektroskopie untersucht. Insbesondere die IR-Messungen zeigen, daß die Koordination über die C=O- und C=N-Gruppierung stattfindet.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H. H. Fox, J. T. Gibas, andA. Metchane, J. Org. Chem.21, 356 (1956).

    Google Scholar 

  2. C. Graig, D. Willis, S. D. Rubbo, andJ. Edgeer, Nature (London)176, 34 (1955).

    Google Scholar 

  3. I. M. Issa, R. M. Issa, M. M. Ghoneim, andY. M. Temerk, Egypt. J. Chem.17, 401 (1974).

    Google Scholar 

  4. I. M. Issa, R. M. Issa, Y. M. Temerk, andM. M. Ghoneim, Mh. Chem.104, 963 (1973).

    Google Scholar 

  5. R. M. Issa, M. F. El-Shazly, andM. F. Iskander, Z. anorg. allg. Chem.354, 90 (1967).

    Google Scholar 

  6. Y. M. Temerk andM. M. Ghoneim, Mh. Chem.106, 1317 (1975).

    Google Scholar 

  7. H. Ohta, Bull. Chem. Soc. Japan,31, 1056 (1958);33, 2 (1960).

    Google Scholar 

  8. L. Sacconi, J. Amer. Chem. Soc.74, 4503 (1952);76, 3400 (1954).

    Google Scholar 

  9. G. Stuve, J. Prakt. Chem.50, 295 (1895);52, 170 (1895).

    Google Scholar 

  10. W. Scott andH. Furman, Standard Methods of Chem. Analysis, 6th ed. Van Nostrand. 1962.

  11. H. T. S. Britton, Hydrogen Ions, 4th ed. Chapman and Hall. 1952.

  12. G. H. Yoe andG. A. Jones, Indust. Eng. Chem. Analyst., Ed.16, 111 (1944).

    Google Scholar 

  13. E. I. Asmus, Z. Anal. Chem.178, 104 (1960).

    Google Scholar 

  14. P. Jop, Compt. Rend.180, 928 (1925).

    Google Scholar 

  15. F. G. Sherief andA. M. Awad, J. Inorg. Nuclear Chem.24, 179 (1962).

    Google Scholar 

  16. A. E. Harvey andD. L. Manning, J. Amer. Chem. Soc.72, 4488 (1950).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Assiut University, Assiut, Egypt

    I. M. Issa, Y. M. Temerk, A. Z. Abu Zhuri, M. S. El-Meligy & M. M. Kamal

Authors
  1. I. M. Issa
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Y. M. Temerk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. Z. Abu Zhuri
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. S. El-Meligy
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. M. Kamal
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Deceased December 1977.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Issa, I.M., Temerk, Y.M., Abu Zhuri, A.Z. et al. Studies on the reaction of salicylidenebenzoic-hydrazide (SBH) with Ce3+, Th4+ and UO2 2+ . Monatshefte für Chemie 111, 1151–1158 (1980). https://doi.org/10.1007/BF00909672

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00909672

Keywords

Search

Navigation