Abstract
Complexes of some rare earth elements (La, CeIII and Y) with salicylaldehyde and o-hydroxybenzoylhydrazide of formula La(o-Bh)3(Sald)3·4 H2O, La(o-Bh)6(Sald)3, Ce(o-Bh)6(Sald)3, and Y(o-Bh)5(Sald)3·2 H2O were isolated. These complexes were identified by elementary analysis and characterized by X-ray crystallography, thermogravimetric analysis and IR absorption spectroscopy. Coordination sites of o-hydroxybenzoylhydrazide are discussed with reference to the characteristic IR absorption bands of the CONHNH2 and phenolic OH groups.
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Abbreviations
- o-Bh :
-
o-Hydroxybenzolhydrazid
- Stald :
-
Salicylaldehyd
Literatur
K. K. Rohatgi undS. K. Sen Gupta, J. inorg. nucl. Chem.34, 3061 (1972).
K. K. rohatgi undS. K. Sen Gupta, J. Indian Chem. Soc.46, 579 (1969).
K. K. Rohatgi undS. K. Sen Gupta, J. inorg. nucl. Chem.32, 2247 (1970).
K. K. Rohatgi undS. K. Sen Guptaibid.31 1203 (1969).
J. Mach, Mh. Chem.104, 564 (1973).
R. G. Charles, J. inorg. nucl. Chem.26, 2298 (1964).
M. Mashima, Bull. Chem. Soc. Japan35, 332, 338, 423, 1882 (1962).
K. E. Jabalpurwala, K. A. Venkatachalam undM. B. Kabaldi, J. inorg. nucl. Chem.26, 1627 (1964);P. V. Gogorischvili, Ju. Ja. Charitonov, M. V. Karkarischvili undR. I. Matschchoschvili, J. neorg. Chim. UdSSR1969, 2891; Chem. Abstr.72, 36430p (1970);R. M. Isso, M. F. El Shazly undM. F. Iskander, Z. anorg. allgem. Chem.354, 90 (1967) und weitere dort angeführte Literaturzitierungen.
A. K. Babko undL. L. Schevtschenko, J. neorg. Chim. UdSSR9, 42 (1964); Chem. Abstr.60, 8781 (1964).
C. M. Harris undE. Sinn, J. inorg. nucl. Chem.30, 1805, 2723 (1968);T. Tokii, Y. Muto, M. Kato, K. Imai, undH. B. Jonassen, ibid. J. inorg. nucl. Chem.34, 2377 (1972).
G. R. Burns, Inorg. Chem.7, 277 (1968).
L. J. Bellamy undR. F. Branch, J. Chem. Soc. [London]1954, 4491;L. J. Bellamy undL. Beecher, ibid. J. Chem. Soc. [London]1954, 4487.
K. Brodersen undH. J. Becher, Chem. Ber.89, 1487 (1956);K. Brodersen, Z. anorg. allgem. Chem.290, 24 (1959);D. Nicholls, M. Rowley undR. Swindels, J. Chem. Soc.A 1966, 950;C. H. Stapfer undR. W. D'Andrea, Inorg. Chem.10, 1224 (1971).
R. C. Aggarwal, B. N. Yadav undT. Prasad, J. inorg. nucl. Chem.35, 427 (1973).
J. B. Jensen, Acta Chem. Scand.10, 667 (1956).
D. Prevoršek, Bull. Soc. Chim. France1958, 795.
R. Přibil, Chem. listý50, 1440 (1956).
S. M. F. Rahman, J. Ahmad undM. M. Haq, J. inorg. nucl. Chem.35, 1011 (1973);33, 4351 (1971);J. R. Durig, S. Chatterjee, J. M. Casper undJ. D. Odoom, ibid. J. inorg. nucl. Chem.34, 1805 (1972).
D. Glavič, J. Slivnik undA. Bole,ibid.35, 427 (1973);C. H. Stapfer, R. W. D'Andrea undR. H. Herber, Inorg. Chem.11, 204 (1972).
G. C. Percy undD. A. Thorton, J. inorg. nucl. Chem.34, 3357 (1972) mit Literaturzitierungen in5.
N. K. Dutt undD. Majumdar, J. inorg. nucl. Chem.34, 657 (1972).
L. J. Bellamy, The Infrared Spectra of Complex Molecules. London: Methuen & Ltd. 1954.
N. B. Colthup, L. H. Paly undS. e. Wiberley, Introduction to Infrared and Raman Spectroscopy. New York: Academic Press. 1964.
B. S. Panu undS. L. Chopra, Z. anorg. allgem. Chem.398, 83 (1973).
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Mach, J. Tris-(salicylaldehydato)-Komplexe einiger Seltenerdelemente mit o-Hydroxybenzoylhydrazid. Monatshefte für Chemie 104, 1539–1550 (1973). https://doi.org/10.1007/BF00909640
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DOI: https://doi.org/10.1007/BF00909640