New tin-containing unsaturated glycol ethers

  • M. F. Shostakovskii
  • A. S. Atavin
  • E. P. Vyalykh
  • B. A. Trofimov
  • R. D. Yakubov
Brief Communications
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Conclusions

  1. 1.

    New unsaturated diethers of glycols, which are derivatives of vinyl alcohol and 3-(triethyltin)propyn-3-ol-1, were obtained by the reaction of sodium-3-propynyloxyalkylvinyl ethers with triethylchlorotin.

     
  2. 2.

    The behavior of the synthesized vinyl ethers under electrophilic addition and cationic polymerization conditions was studied. The tinacetylenic fragment is split at the Sn- C≡ bond by electrophilic reagents, while practically completely suppressing the reactivity of the vinyloxy-group.

     

Keywords

Polymerization Alcohol Ether Glycol Vinyl 

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Copyright information

© Consultants Bureau 1968

Authors and Affiliations

  • M. F. Shostakovskii
    • 1
  • A. S. Atavin
    • 1
  • E. P. Vyalykh
    • 1
  • B. A. Trofimov
    • 1
  • R. D. Yakubov
    • 1
  1. 1.Irkutsk Institute of Organic Chemistry, Siberian BranchAcademy of Sciences of the USSRUSSR

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