On the reaction of methyl dichlorophosphine with acrylamide

  • V. K. Khairullin
  • R. M. Kondrat'eva
  • A. N. Pudovik
Brief Communications

Conclusions

  1. 1.

    The following compounds are formed by the reaction of methyl dichlorophosphine with acrylamide: methyl-β-cyanoethylphosphonyl chloride (36.6%),β-chloropropionitrile (16.2%) and methyl-β-cyanoettylphosphonic acid (3.4%).

     
  2. 2.

    The reaction of methyl-β-cyanoethylphosphonyl chloride with water (2∶1) gave methyl-β-cyanoethylphosphonic acid anhydride.

     
  3. 3.

    By reacting methyl-β-cyanoethylphosphonyl chloride with alcohols and diethylamine, we have obtained a number of esters and the diethylamide of methyl-β-cyanoethylphosphonic acid.

     

Keywords

Alcohol Methyl Chloride Ester Anhydride 

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Literature cited

  1. 1.
    V. K. Khairullin, M. A. Vasyanina, and A. N. Pudovik, Izv. AN SSSR, Ser. khim.,1967, 1603.Google Scholar
  2. 2.
    Belsteins Handbuch der organischen Chemie, Berlin, 1920,2, p. 250.Google Scholar

Copyright information

© Consultants Bureau 1968

Authors and Affiliations

  • V. K. Khairullin
    • 1
  • R. M. Kondrat'eva
    • 1
  • A. N. Pudovik
    • 1
  1. 1.A. E. Arbuzov Institute of Inorganic and Physical ChemistryAcademy of Sciences of the USSRUSSR

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