Fluorine-containingβ-sultones

Communication 22. The mechanism of formation of polyfluoroalkenylsulfuric acid derivatives
  • G. A. Sokol'skii
  • M. A. Belaventsev
  • I. L. Knunyants
Organic and Biological Chemistry

Conclusions

  1. 1.

    The reactions of fluorine-containingβ-sultones with esters and acid chlorides of nitrous, phosphoric or phosphonic, sulfurous, sulfuric and sulfonic acids take place as transacylations, forming esters or acid chlorides of polyfluoroalkenylsulfuric acids and acid fluorides of the corresponding nitrogen, phosphorus or sulfur-containing acids.

     
  2. 2.

    Unsymmetrical dialkyl sulfates are characterized by twofold activity: alkylation takes place with the simpler alkyl radical; but acylation involves the alkoxyl group with the larger hydrocarbon residue.

     

Keywords

Nitrogen Sulfate Chloride Ester Phosphorus 

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Literature cited

  1. 1.
    G. A. Sokol'skii, M. A. Belaventsev, and I. L. Knunyants, Izv. AN SSSR, Ser. khim.,1965, 1804.Google Scholar
  2. 2.
    I. L. Knunyants, G. A. Sokol'skii, and M. A. Belaventsev, Izv. AN SSSR, Ser. khim.,1966, 1017.Google Scholar
  3. 3.
    I. L. Knunyants, G. A. Sokol'skii, and M. A. Belaventsev, Izv. AN SSSR, Ser. khim.,1966, 1022.Google Scholar
  4. 4.
    I. L. Knunyants, G. A. Sokol'skii, and M. A. Belaventsev, Izv. AN SSSR, Ser. khim.,1966, 1027.Google Scholar
  5. 5.
    C. Suter, Chemistry of Organic Sulfur Compounds,[Russian translation], Foreign Literature Press,1, 60 (1960).Google Scholar
  6. 6.
    M. A. Belaventsev, G. A. Sokol'skii, and I. L. Knunyants, Izv. AN SSSR, Ser. khim.,1965, 1613.Google Scholar

Copyright information

© Consultants Bureau 1968

Authors and Affiliations

  • G. A. Sokol'skii
  • M. A. Belaventsev
  • I. L. Knunyants

There are no affiliations available

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