Infrared absorption spectra of zirconium rhodanide complexes

  • Yu. Ya. Kharitonov
  • I. A. Rozanov


  1. 1.

    A description is given of the infrared absorption spectra (400–4000 cm−1) of the compound ZrO(NCS)2 · MNCS · 2H2O, where M=NH4, K, Rb, Cs, or PyH, as well as of the compounds (PyH)2[Zr(NCS)6] · 2H2O and ZrOCl2 · 8H2O (in the sofid state).

  2. 2.

    The ZrO(NCS)2 · MNCS · 2H2O complexes contain the zirconyl group, ZrO, and monodentate rhodano-groups, bound with a zirconium atom through a nitrogen atom. Hydrogen bonds apparently exist in the compounds.

  3. 3.

    The compound ZrOCl2 · 8H2O does not contain the zirconyl group, in complete agreement with structural data.



Hydrogen Nitrogen 2H2O Zirconium Hydrogen Bond 
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Copyright information

© Consultants Bureau 1963

Authors and Affiliations

  • Yu. Ya. Kharitonov
    • 1
  • I. A. Rozanov
    • 1
  1. 1.N. S. Kurnakov Institute of General and Inorganic ChemistryAcademy of SciencesUSSR

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