Infrared absorption spectra of zirconium rhodanide complexes

  • Yu. Ya. Kharitonov
  • I. A. Rozanov
Article

Summary

  1. 1.

    A description is given of the infrared absorption spectra (400–4000 cm−1) of the compound ZrO(NCS)2 · MNCS · 2H2O, where M=NH4, K, Rb, Cs, or PyH, as well as of the compounds (PyH)2[Zr(NCS)6] · 2H2O and ZrOCl2 · 8H2O (in the sofid state).

     
  2. 2.

    The ZrO(NCS)2 · MNCS · 2H2O complexes contain the zirconyl group, ZrO, and monodentate rhodano-groups, bound with a zirconium atom through a nitrogen atom. Hydrogen bonds apparently exist in the compounds.

     
  3. 3.

    The compound ZrOCl2 · 8H2O does not contain the zirconyl group, in complete agreement with structural data.

     

Keywords

Hydrogen Nitrogen 2H2O Zirconium Hydrogen Bond 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    I. V. Tananaev and I. A. Rozanov, Zh. neorgan. khimii. (in press).Google Scholar
  2. 2.
    C. G. Barraclough, J. Lewis, and R. S. Nyhofm, J. Chem. Soc. 1959, 3552.Google Scholar
  3. 3.
    Yu. Ya. Kharitonov and Yu. A. Buslaev, Izv. AN SSSR. Otd. khim. n. 1962, 393.Google Scholar
  4. 4.
    A. Clearfield and P. A. Vaughan, Acta Crystallogr.9, 555 (1956).Google Scholar
  5. 5.
    G. C. Pimentel and A. L. McClellan, The Hydrogen Bond, San Francisco-London, W. H. Freeman and C°, 1960.Google Scholar
  6. 6.
    L. H. Jones, J. Chem. Phys.25, 1069 (1956);28, 1234 (1958).Google Scholar
  7. 7.
    M. M. Chamberlain and J. C. Bailar, J. Amer. Chem. Soc.81, 6412 (1959).Google Scholar
  8. 8.
    P. C. H. Mitchell and R. J. P. Williams, J. Chem. Soc. 1960, 1912.Google Scholar
  9. 9.
    A. Tramer, Compt. rend.250, 3150 (1960).Google Scholar
  10. 10.
    J. Chatt and L. A. Duncanson, Nature178, 997 (1956).Google Scholar
  11. 11.
    L. Vallarino, J. Chem. Soc. 1957, 2473.Google Scholar
  12. 12.
    J. Chatt, L. A. Duncanson, F. A. Hart, and P. G. Owston, Nature181, 43 (1958).Google Scholar
  13. 13.
    Coflection: “Application of Spectroscopy to Chemistry” [Russian translation] IL., M., 1959, pp. 427–428.Google Scholar
  14. 14.
    R. E. Kitson and N. E. Griffith, Analyt. Chem.24, 334 (1952).Google Scholar
  15. 15.
    V. N. Filimonov, D. S. Bystrov, and A. N. Terenin, Opt. i spektr.3, 480 (1957).Google Scholar
  16. 16.
    H. J. Coerver and C. Curran. J. Amer. Chem. Soc.80, 3522 (1958).Google Scholar
  17. 17.
    W. Gerrard, M. F. Lappert, H. Pyszora, and J. W. Wallis, J. Chem. Soc. 1960, 2182.Google Scholar
  18. 18.
    G. S. Rao, Z. anorgan. Chem.304, 351 (1960).Google Scholar
  19. 19.
    Yu. Ya. Kharitonov, Ni Tsia-Tsan, and A. V. Babaeva, Dokl. AN SSSR141, 645 (1961).Google Scholar
  20. 20.
    L. Bellamy, Infrared Spectra of Mofecules [Russian translation] IL., M., 1957, p. 409.Google Scholar
  21. 21.
    N. S. Gill, R. H. Nuttall, D. E. Scaife, and D. W. A. Sharp, J. Morgan, and Nucl. Chem.18, 79 (1961).Google Scholar
  22. 22.
    P. Babu Rao and K. Sreerama Murty, Current Sci.29, 14 (1960).Google Scholar
  23. 23.
    H. J. Eichoff and F. Weigel, Z. anorgan. Chem.275, 267 (1954).Google Scholar

Copyright information

© Consultants Bureau 1963

Authors and Affiliations

  • Yu. Ya. Kharitonov
    • 1
  • I. A. Rozanov
    • 1
  1. 1.N. S. Kurnakov Institute of General and Inorganic ChemistryAcademy of SciencesUSSR

Personalised recommendations