Kinetics of dehydrogenation and dehydration of isopropyl alcohol on titanium dioxide (anatase)

  • A. A. Tolstopyatova
  • I. R. Konenko
  • A. A. Balandin
Article
  • 137 Downloads

Summary

  1. 1.

    This is the first study that has been made of the detailed kinetics of the dehydrogenation and dehydration of isopropyl alcohol on TiO2, complicated by carbonation of the catalyst.

     
  2. 2.

    The carbonation of the TiO2 has little effect on the values of the relative adsorbtion coefficient of acetone and hydrogen.

     
  3. 3.

    The relative adsorbtion coefficients of acetone and water drop with increasing temperature (from 2.7 to 0.9 for acetone, and from 1.9 to 0.9 for water), but the coefficients of hydrogen and propylene do not change over the temperature range 280–310‡.

     

Keywords

Hydrogen Alcohol TiO2 Titanium Dioxide 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    F. Bischoff and H. Adkins, J. Amer. Chem. Soc.47, 807 (1925).Google Scholar
  2. 2.
    F. Bischoff and H. Adkins, J. Amer. Chem. Soc.46, 256 (1924).Google Scholar
  3. 3.
    A. M. Rubinshtein and S. G. Kulikov, Dokl. AN SSSR67, 1053 (1949).Google Scholar
  4. 4.
    A. M. Rubinshtein and S. G. Kulikov, Izv. AN SSSR, Otd. khim. n.1950, 84.Google Scholar
  5. 5.
    G. Schwab and E. Schwab, J. Amer. Chem. Soc.71, 1806 (1949).Google Scholar
  6. 6.
    C. I. Englder, J. Phys. Chem.21, 676 (1917).Google Scholar
  7. 7.
    Yu. A. Arbuzov and N. D. Zelinskii, Compt. rend.30, 717 (1941).Google Scholar
  8. 8.
    Küchi Ioschioka, Japanese patent 180692; October 20, 1949.Google Scholar
  9. 9.
    W. Krantz, US patent 2605238; July 29, 1950.Google Scholar
  10. 10.
    V. Johnson, British patent 680122; October 29, 1952.Google Scholar
  11. 11.
    F. Spangenberg, Industr. J. quim. Buenos Aires7, 393 (1945).Google Scholar
  12. 12.
    M. Brown and A. Vernon, Industr. and Engng. Chem.32, 534 (1940).Google Scholar
  13. 13.
    F. Gresham and M. Brunes, US patent 2422169; June 10, 1947.Google Scholar
  14. 14.
    K. Bunte and H. Bruckner, Brennstoff-Chemie22, 205 (1941).Google Scholar
  15. 15.
    V. C. F. Holm and R. W. Blue, Industr. and Engng. Chem.44, 107 (1952).Google Scholar
  16. 16.
    I. L. Sandler, J. Phys. Chem.58, 58 (1954).Google Scholar
  17. 17.
    K. Hauffe, Angew. Chemie67, 189 (1955).Google Scholar
  18. 18.
    A. A. Balandin, A. A. Tolstopyatova, and I. R. Konenko, Dokl. AN SSSR133, 130 (1960); Izv. AN SSSR, Otd. khim. n.1960, 2096.Google Scholar
  19. 19.
    G. Moger and W. Rouge, Angew. Chemie52, 637 (1939).Google Scholar
  20. 20.
    V. V. Patrikeev and V. A. Ferapontov, Peredovoi nauchno-tekhnich. i proizvodstven. opyt. No. P-57-75/11 (1957).Google Scholar
  21. 21.
    A. A. Balandin, Zh. obshch. khimii12, 153, 160 (1942).Google Scholar
  22. 22.
    A. A. Balandin, O. K. Bogdanova, and A. P. Shcheglova, Izv. AN SSSR, Otd. khim. n.1946, 464.Google Scholar
  23. 23.
    A. A. Balandin, Dokl. AN SSSR63, 33 (1948).Google Scholar
  24. 24.
    A. A. Tolstopyatova, A. A. Balandin, and é. N. Dmitriev, Izv. AN SSSR, Otd. khim. n. 1956, 1404.Google Scholar

Copyright information

© Consultants Bureau Enterprises, Inc. 1961

Authors and Affiliations

  • A. A. Tolstopyatova
    • 1
  • I. R. Konenko
    • 1
  • A. A. Balandin
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

Personalised recommendations