Advertisement

Tautomerism of nitro compounds

Communication 3. The influence of temperature and ion strength of solutions on the rate of tautomeric conversion of phenylnitromethane
  • V. M. Belikov
  • S. G. Mairanovskii
  • Ts. B. Korchemnaya
  • S. S. Novikov
Article
  • 22 Downloads

Summary

  1. 1.

    The comparatively small dissociation rate of aciphenylnitromethane is explained by a significant steric factor. The recombination of phenylnitromethane proceeds normally.

     
  2. 2.

    The ion strength of the solutions has very little influence on the rate of the processes studied.

     

Keywords

Recombination Dissociation Rate Nitro Compound Steric Factor Small Dissociation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    S. G. Mairanovskii, V. M. Belikov, Ts. B. Korchemnaya, V. A. Klimova, and S. S. Novikov, Izv. AN SSSR. Otd. Khim. Nauk1960, 1787.Google Scholar
  2. 2.
    R. P. Bell, Quart. Revs.13, N 3, 169 (1959).Google Scholar
  3. 3.
    G. G. Hammes and L. E. Erickson, J. Chem. Educ.35, 612 (1958).Google Scholar
  4. 4.
    A. I. Shatenshtein, Theory of Acids and Bases, Goskhimizdat, M.-L. (1949), p. 196 [in Russian].Google Scholar

Copyright information

© Consultants Bureau 1961

Authors and Affiliations

  • V. M. Belikov
    • 1
  • S. G. Mairanovskii
    • 1
  • Ts. B. Korchemnaya
    • 1
  • S. S. Novikov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

Personalised recommendations