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Cyclische Ester von Phosphin- und Thiophosphinsäuren

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Zusammenfassung

Chlormethyl-methyl-phosphinsäurechlorid (ClCH2)(CH3)P(O)Cl und Chlormethyl-methyl-thiophosphinsäurechlorid (ClCH2)(CH3)-P(S)Cl reagieren mit aromatische 1,2-Diolen wie Brenzcatechin, mit o-Aminophenol, o-Aminothiophenol und Toluol-3,4-dithiol unter Substitution der beiden Chloratome zu den entsprechenden Benzophosphorinanen.

Abstract

(ClCH2)(CH3)P(O)Cl and (ClCH2)(CH3)P(S)Cl react with aromatic diols like catechol, o-aminophenol, o-aminothiophenol and toluene-3,4-dithiol with the formation of benzophosphorinanes.

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Authors and Affiliations

  1. Institut für Anorganische Chemie der Universität Würzburg, Würzburg, Deutschland

    M. Wieber & B. Eichhorn

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  1. M. Wieber
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  2. B. Eichhorn
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Wieber, M., Eichhorn, B. Cyclische Ester von Phosphin- und Thiophosphinsäuren. Monatshefte für Chemie 99, 261–266 (1968). https://doi.org/10.1007/BF00908928

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  • DOI: https://doi.org/10.1007/BF00908928

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