Synthesis of aryl fluorides by decomposition of aryldiazonium hexafluorogermanates

  • L. G. Makarova
  • I. V. Polovyanyuk
Brief Communications


Seven aryldiazonium hexafluorogermanates have been synthesized, and the corresponding aryl fluorides have been prepared from them in 60–75% yield, by thermal decomposition.


Fluoride Thermal Decomposition Aryl Fluoride Hexafluorogermanates 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    G. Balz and G. Schieman, Ber.,60, 1186 (1927).Google Scholar
  2. 2.
    A. Roe, Organic Reactions, Coll. 5 [Russian translation], Foreign Lit. Press (1951), p. 155.Google Scholar
  3. 3.
    G. Schieman and V. Winkelmüller, Syntheses of Organic Preparations, Coll. 2 [Russian translation], Foreign Lit. Press (1949), p. 534.Google Scholar
  4. 4.
    B. V. Tronov and E. A. Krüger, Chem. Abstracts,21, 3887 (1927).Google Scholar
  5. 5.
    E. C. Allen and S. Sugden, J. Chem. Soc.,1932, 762.Google Scholar
  6. 6.
    A. F. Holleman and J. Slothouwer, Chem. Abstracts,5, 1905 (1911).Google Scholar
  7. 7.
    G. Schieman, Ber.,62, 1794 (1929).Google Scholar
  8. 8.
    G. Schieman and R. Pillarsky, Ber.,64, 1340 (1931).Google Scholar
  9. 9.
    I. F. Dippy and F. R. Williams, J. Chem. Soc.,1934, 1466.Google Scholar
  10. 10.
    K. G. Rutherford, W. Redmond, and J. Rigamonti, J. Org. Chem.,26, 12 (1961).Google Scholar
  11. 11.
    R. H. Check and R. H. Wiley, J. Am. Chem. Soc.,71, 1863 (1949).Google Scholar

Copyright information

© Consultants Bureau 1968

Authors and Affiliations

  • L. G. Makarova
    • 1
  • I. V. Polovyanyuk
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

Personalised recommendations