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Selective hydrogenation of methyl vinyl ketone and mesityl oxide in the presence of homogeneous rhodium catalysts

  • N. V. Borunova
  • L. Kh. Freidlin
  • M. L. Khidekel'
  • S. S. Daniélova
  • V. A. Avidov
  • P. S. Chekrii
Brief Communications

Conclusions

  1. 1.

    Homogeneous catalysts based on complexes of Rh with tyrosine and N-phenylanthranilic acid possess substantially greater activity than the heterogeneous catalyst Rh-C in reactions of hydrogenation of mesityl oxide and methyl vinyl ketone.

     
  2. 2.

    On a homogeneous rhodium catalyst, just as on a heterogeneous catalyst, the process is selective: only the C=C bond is hydrogenated, while the carbonyl group is not reduced.

     

Keywords

Oxide Hydrogenation Methyl Tyrosine Carbonyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature cited

  1. 1.
    V. A. Avilov, O. N. Efimov, O. N. Eremenko, A. G. Ovcharenko, N. S. Chekrii, and M. L. Khidekel', Summaries of the Second All-Union Conference on Liquid-Phase Catalytic Reactions [in Russian], Alma-Ata (1966).Google Scholar
  2. 2.
    E. F. Litvin, L. Kh. Freidlin, M. L. Khidekel', L. F. Topuridze, V. A. Avilov, and P. S. Chekrii, Summaries of the Second All-Union Conference on Liquid-Phase Catalytic Reactions [in Russian], Alma-Ata (1966).Google Scholar

Copyright information

© Consultants Bureau 1968

Authors and Affiliations

  • N. V. Borunova
    • 1
    • 2
  • L. Kh. Freidlin
    • 1
    • 2
  • M. L. Khidekel'
    • 1
    • 2
  • S. S. Daniélova
    • 1
    • 2
  • V. A. Avidov
    • 1
    • 2
  • P. S. Chekrii
    • 1
    • 2
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR
  2. 2.Branch of the Institute of Chemical PhysicsAcademy of Sciences of the USSRUSSR

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