Acylation of the trinitromethanide ion

  • S. A. Shevelev
  • V. I. Erashko
  • B. G. Sankov
  • A. A. Fainzil'berg
Organic and Biological Chemistry
  • 17 Downloads

Conclusions

  1. 1.

    In the reactions of the ambident trinitromethanide ion with acid chlorides (acetyl and benzoyl chlorides in acetonitrile, and also in 1,2-dimethoxyethane) O-acylation of this anion occurs. The O-acyl derivatives of trinitromethane formed, being extremely reactive compounds, undergo a number of further transformations, leading finally to the mixed acetic (or benzoic) chloroformonitrolic anhydride.

     
  2. 2.

    In the process studied not only the acyl halides, but also the acyl nitrates formed in the course of the reaction, act as acylating agents.

     
  3. 3.

    In the halogenation of the O-acetyl derivative of trinitromethane the corresponding halotrinitromethanes are formed.

     

Keywords

Acetic Chloride Nitrate Acetonitrile Anhydride 

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Copyright information

© Consultants Bureau 1968

Authors and Affiliations

  • S. A. Shevelev
    • 1
  • V. I. Erashko
    • 1
  • B. G. Sankov
    • 1
  • A. A. Fainzil'berg
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

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